Autor segons l'article: Melgar, Dolores; Bandeira, Nuno A. G.; Avalos, Josep Bonet; Bo, Carles;
Departament: Química Física i Inorgànica Enginyeria Química
Autor/s de la URV: Bo Jané, Carles / Bonet Avalos, José
Resum: Keplerates are a family of anionic metal oxide spherical capsules containing up to 132 metal atoms and some hundreds of oxygen atoms. These capsules holding a high negative charge of −12 coordinate both mono-anionic and di-anionic ligands thus increasing their charge up to −42, even up to −72, which is compensated by the corresponding counter-cations in the X-ray structures. We present an analysis of the relative importance of several energy terms of the coordinate bond between the capsule and ligands like carbonate, sulphate, sulphite, phosphinate, selenate, and a variety of carboxylates, of which the overriding component is contributed by solvation/de-solvation effects.
Àrees temàtiques: Química Physics, atomic, molecular & chemical Physics and astronomy (miscellaneous) Physics and astronomy (all) Physical and theoretical chemistry Odontología Medicina ii Medicina i Materiais Matemática / probabilidade e estatística Interdisciplinar Geociências General physics and astronomy General medicine Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, physical Biotecnología Biodiversidade Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: carles.bo@urv.cat josep.bonet@urv.cat
Identificador de l'autor: 0000-0001-9581-2922 0000-0002-7339-9564
Data d'alta del registre: 2024-09-07
Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Physical Chemistry Chemical Physics. 19 (7): 5343-5350
Referència de l'ítem segons les normes APA: Melgar, Dolores; Bandeira, Nuno A. G.; Avalos, Josep Bonet; Bo, Carles; (2017). Anions coordinating anions: analysis of the interaction between anionic Keplerate nanocapsules and their anionic ligands. Physical Chemistry Chemical Physics, 19(7), 5343-5350. DOI: 10.1039/c6cp08511c
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2017
Tipus de publicació: Journal Publications
Repositori URV