Articles producció científica> Enginyeria Química

Molecular design of microcapsule shells for visible light-triggered release

  • Dades identificatives

    Identificador: imarina:5643849
    Autors:
    Pirone DMarturano VDel Pezzo RPrieto SFUnderiner TGiamberini MTylkowski B
    Resum:
    © 2019 by the authors. The development of photo-responsive capsules to tune and control the sustained-release of encapsulated actives is a fascinating and challenging route to improve the performances and effectiveness of a wide range of delivery applications. In this work, we report the preparation of visible light-responsive capsules obtained via oil-in-water interfacial polycondensation between modified diacyl-chloride azobenzene moiety and diamine flexible spacer in the presence of cross-linkers with different structures and functionalities. The effect on the release profile of the encapsulated perfume oil was investigated using three flexible spacers with different lengths (1,8-diaminooctane; 1,6-diaminohexane and 1,4-diaminobutane) and two types of cross-linkers (1,3,5-benzenetricarbonyl trichloride and melamine). We analyzed how the properties of microcapsules can be tailored changing the design of the shell structure. Fine tuning of the perfume release profiles was obtained. The changes in capsules size and morphology due to visible light irradiation were monitored via light scattering, optical microscopy and atomic force microscopy. Perfume release was 50% faster in the systems prepared with melamine as the cross-linker. Modelling studies were carried out to support the discussion of the experimental results.
  • Altres:

    Autor segons l'article: Pirone D; Marturano V; Del Pezzo R; Prieto SF; Underiner T; Giamberini M; Tylkowski B
    Departament: Enginyeria Química
    e-ISSN: 2073-4360
    Autor/s de la URV: Giamberini, Marta / Tylkowski, Bartosz
    Paraules clau: Robust Polymers Polymerization Photo-triggered release Modified azobenzene Fabrication Essential oils Encapsulation Delivery modified azobenzene encapsulation
    Resum: © 2019 by the authors. The development of photo-responsive capsules to tune and control the sustained-release of encapsulated actives is a fascinating and challenging route to improve the performances and effectiveness of a wide range of delivery applications. In this work, we report the preparation of visible light-responsive capsules obtained via oil-in-water interfacial polycondensation between modified diacyl-chloride azobenzene moiety and diamine flexible spacer in the presence of cross-linkers with different structures and functionalities. The effect on the release profile of the encapsulated perfume oil was investigated using three flexible spacers with different lengths (1,8-diaminooctane; 1,6-diaminohexane and 1,4-diaminobutane) and two types of cross-linkers (1,3,5-benzenetricarbonyl trichloride and melamine). We analyzed how the properties of microcapsules can be tailored changing the design of the shell structure. Fine tuning of the perfume release profiles was obtained. The changes in capsules size and morphology due to visible light irradiation were monitored via light scattering, optical microscopy and atomic force microscopy. Perfume release was 50% faster in the systems prepared with melamine as the cross-linker. Modelling studies were carried out to support the discussion of the experimental results.
    Àrees temàtiques: Polymers and plastics Polymer science Odontología General chemistry Farmacia Engenharias ii Ciências biológicas ii Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 20734360
    Adreça de correu electrònic de l'autor: bartosz.tylkowski@urv.cat marta.giamberini@urv.cat
    Identificador de l'autor: 0000-0002-4163-0178 0000-0001-8278-3552
    Data d'alta del registre: 2023-02-18
    Volum de revista: 11
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://www.mdpi.com/2073-4360/11/5/904
    Referència a l'article segons font original: Polymers. 11 (5):
    Referència de l'ítem segons les normes APA: Pirone D; Marturano V; Del Pezzo R; Prieto SF; Underiner T; Giamberini M; Tylkowski B (2019). Molecular design of microcapsule shells for visible light-triggered release. Polymers, 11(5), -. DOI: 10.3390/polym11050904
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.3390/polym11050904
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2019
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Chemistry (Miscellaneous),Polymer Science,Polymers and Plastics
    Robust
    Polymers
    Polymerization
    Photo-triggered release
    Modified azobenzene
    Fabrication
    Essential oils
    Encapsulation
    Delivery
    modified azobenzene
    encapsulation
    Polymers and plastics
    Polymer science
    Odontología
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas ii
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Astronomia / física
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