Activación de diboranos: una fuente de inspiración en síntesis

Identificador:  imarina:6364717

Handle: https://hdl.handle.net/20.500.11797/imarina6364717

Autors:  Elena Fernández Gutiérrez

Resum:
The benefits from diboron reagents in organic synthesis are several and represent a source of innovation in the C-B bond genera- tion with high precision and ef ciency. The activation of the diboron reagents has been considered of great importance due to the ability to cleavage the B-B bond in a homo- and heterolytic way. The nature of the diboron reagents justi es their activation via organocatalytic methods or with transition metal complexes, which essentially generate boryl groups with electrophilic and nucleophilic character, which might react in a direct way.