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Discovery and Supramolecular Interactions of Neutral Palladium-Oxo Clusters Pd-16 and Pd-24

  • Dades identificatives

    Identificador: imarina:9099572
    Autors:
    Bhattacharya, SauravBasu, UttaraHaouas, MohamedSu, PeiEspenship, Michael ForresterWang, FeiSole-Daura, AlbertTaffa, Dereje H.Wark, MichaelPoblet, Josep M.Laskin, JuliaCadot, EmmanuelKortz, Ulrich
    Resum:
    We report on the synthesis, structure, and physicochemical characterization of the first three examples of neutral palladium-oxo clusters (POCs). The 16-palladium(II)-oxo cluster [Pd16O24(OH)(8)((CH3)(2)As)(8)] (Pd-16) comprises a cyclic palladium-oxo unit capped by eight dimethylarsinate groups. The chloro-derivative [Pd16Na2O26(OH)(3) Cl-3 ((CH3)(2) As)(8)] (Pd16Cl) was also prepared, which forms a highly stable 3D supramolecular lattice via strong intermolecular interactions. The 24-palladium(II)-oxo cluster [Pd24O44(OH)(8)((CH3)(2)As)(16)] (Pd-24) can be considered as a bicapped derivative of Pd-16 with a tetra-palladium-oxo unit grafted on either side. The three compounds were fully characterized 1) in the solid state by single-crystal and powder XRD, IR, TGA, and solid-state H-1 and C-13 NMR spectroscopy, 2) in solution by H-1, C-13 NMR and H-1 DOSY spectroscopic methods, and 3) in the gas phase by electrospray ionization mass spectrometry (ESI-MS).
  • Altres:

    Autor segons l'article: Bhattacharya, Saurav; Basu, Uttara; Haouas, Mohamed; Su, Pei; Espenship, Michael Forrester; Wang, Fei; Sole-Daura, Albert; Taffa, Dereje H.; Wark, Michael; Poblet, Josep M.; Laskin, Julia; Cadot, Emmanuel; Kortz, Ulrich;
    Departament: Química Física i Inorgànica
    Autor/s de la URV: Poblet Rius, Josep Maria / Solé Daura, Albert / Wang, Fei
    Paraules clau: Water oxidation Supramolecular interactions Supramolecular chemistry Spectroscopic method Spectroscopic analysis Single-molecule magnets Single-crystal and powder Single crystals Precise Polyoxopalladium Physico-chemical characterization Palladium compounds Palladium Organic– Organic–inorganic frameworks Nuclear magnetic resonance spectroscopy Neutral clusters Mass spectrometry Ionization of gases Intermolecular interactions Inorganic frameworks Inorganic chemistry Hydrogen-bonds Frameworks Family Electrospray ionization mass spectrometry Electrospray ionization Electrodeposition Crystal Cl Chloro derivatives Chlorine compounds Chemistry Building-blocks 13c nmr spectroscopy
    Resum: We report on the synthesis, structure, and physicochemical characterization of the first three examples of neutral palladium-oxo clusters (POCs). The 16-palladium(II)-oxo cluster [Pd16O24(OH)(8)((CH3)(2)As)(8)] (Pd-16) comprises a cyclic palladium-oxo unit capped by eight dimethylarsinate groups. The chloro-derivative [Pd16Na2O26(OH)(3) Cl-3 ((CH3)(2) As)(8)] (Pd16Cl) was also prepared, which forms a highly stable 3D supramolecular lattice via strong intermolecular interactions. The 24-palladium(II)-oxo cluster [Pd24O44(OH)(8)((CH3)(2)As)(16)] (Pd-24) can be considered as a bicapped derivative of Pd-16 with a tetra-palladium-oxo unit grafted on either side. The three compounds were fully characterized 1) in the solid state by single-crystal and powder XRD, IR, TGA, and solid-state H-1 and C-13 NMR spectroscopy, 2) in solution by H-1, C-13 NMR and H-1 DOSY spectroscopic methods, and 3) in the gas phase by electrospray ionization mass spectrometry (ESI-MS).
    Àrees temàtiques: Química Medicina ii Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: fei.wang@urv.cat josepmaria.poblet@urv.cat
    Identificador de l'autor: 0000-0001-5106-5793 0000-0002-4533-0623
    Data d'alta del registre: 2024-07-27
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202010690
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Angewandte Chemie (International Ed. Print). 60 (7): 3632-3639
    Referència de l'ítem segons les normes APA: Bhattacharya, Saurav; Basu, Uttara; Haouas, Mohamed; Su, Pei; Espenship, Michael Forrester; Wang, Fei; Sole-Daura, Albert; Taffa, Dereje H.; Wark, Mic (2021). Discovery and Supramolecular Interactions of Neutral Palladium-Oxo Clusters Pd-16 and Pd-24. Angewandte Chemie (International Ed. Print), 60(7), 3632-3639. DOI: 10.1002/anie.202010690
    DOI de l'article: 10.1002/anie.202010690
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2021
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Water oxidation
    Supramolecular interactions
    Supramolecular chemistry
    Spectroscopic method
    Spectroscopic analysis
    Single-molecule magnets
    Single-crystal and powder
    Single crystals
    Precise
    Polyoxopalladium
    Physico-chemical characterization
    Palladium compounds
    Palladium
    Organic– Organic–inorganic frameworks
    Nuclear magnetic resonance spectroscopy
    Neutral clusters
    Mass spectrometry
    Ionization of gases
    Intermolecular interactions
    Inorganic frameworks
    Inorganic chemistry
    Hydrogen-bonds
    Frameworks
    Family
    Electrospray ionization mass spectrometry
    Electrospray ionization
    Electrodeposition
    Crystal
    Cl
    Chloro derivatives
    Chlorine compounds
    Chemistry
    Building-blocks
    13c nmr spectroscopy
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Astronomia / física
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