Articles producció científica> Química Analítica i Química Orgànica

Perfecting self-organization of covalent and supramolecular mega macromolecules via sequence-defined and monodisperse components

  • Dades identificatives

    Identificador: imarina:9138917
    Autors:
    Percec VXiao QLligadas GMonteiro MJ
    Resum:
    © 2020 Elsevier Ltd Biological macromolecules such as nucleic acids and proteins are homochiral, display monodisperse chain length with mega, multimillion, molecular weight and encode functions by their precise sequence via self-organization. The functions of biological macromolecules are either independent on molecular weight or, like in the case of ribosome, are programmed by the self-organization of their mega molecular weight. In spite of the fact that Staudinger coined the name macromolecule 100 years ago, self-organizable synthetic covalent and supramolecular mega macromolecules exhibiting the symptoms of biological macromolecules started to emerge only recently. This personal perspective will discuss, with examples mostly from our laboratory, methodologies for the synthesis of self-organizable covalent and supramolecular mega macromolecules for which functions are encoded, programmed and perfected via homochiral, sequence-defined and monodisperse components. Methodologies to generate them together with historical developments will be briefly discussed.
  • Altres:

    Autor segons l'article: Percec V; Xiao Q; Lligadas G; Monteiro MJ
    Departament: Química Analítica i Química Orgànica
    Autor/s de la URV: Lligadas Puig, Gerard
    Paraules clau: Sequence-defined Self-interrupted Monodisperse Mega Macromolecules
    Resum: © 2020 Elsevier Ltd Biological macromolecules such as nucleic acids and proteins are homochiral, display monodisperse chain length with mega, multimillion, molecular weight and encode functions by their precise sequence via self-organization. The functions of biological macromolecules are either independent on molecular weight or, like in the case of ribosome, are programmed by the self-organization of their mega molecular weight. In spite of the fact that Staudinger coined the name macromolecule 100 years ago, self-organizable synthetic covalent and supramolecular mega macromolecules exhibiting the symptoms of biological macromolecules started to emerge only recently. This personal perspective will discuss, with examples mostly from our laboratory, methodologies for the synthesis of self-organizable covalent and supramolecular mega macromolecules for which functions are encoded, programmed and perfected via homochiral, sequence-defined and monodisperse components. Methodologies to generate them together with historical developments will be briefly discussed.
    Àrees temàtiques: Química Polymers and plastics Polymer science Organic chemistry Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Biotecnología Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0032-3861
    Adreça de correu electrònic de l'autor: gerard.lligadas@urv.cat
    Identificador de l'autor: 0000-0002-8519-1840
    Data d'alta del registre: 2023-02-23
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://www.sciencedirect.com/science/article/pii/S0032386120310776?dgcid=rss_sd_all
    Referència a l'article segons font original: Polymer. 211 (123252):
    Referència de l'ítem segons les normes APA: Percec V; Xiao Q; Lligadas G; Monteiro MJ (2020). Perfecting self-organization of covalent and supramolecular mega macromolecules via sequence-defined and monodisperse components. Polymer, 211(123252), -. DOI: 10.1016/j.polymer.2020.123252
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.1016/j.polymer.2020.123252
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2020
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Materials Chemistry,Organic Chemistry,Polymer Science,Polymers and Plastics
    Sequence-defined
    Self-interrupted
    Monodisperse
    Mega
    Macromolecules
    Química
    Polymers and plastics
    Polymer science
    Organic chemistry
    Medicina ii
    Materials chemistry
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Biotecnología
    Astronomia / física
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