Autor segons l'article: Armengol-Relats, Helena; Mato, Mauro; Escofet, Imma; Echavarren, Antonio M.;
Departament: Química Analítica i Química Orgànica
Autor/s de la URV: Armengol Relats, Helena / ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro
Paraules clau: Synthesis (chemical) Rhodium compounds Rhodium Retro-buchner reaction Propargylic esters Organometallics Organometallic intermediates Molecular architecture Metals Metal-carbene intermediates Metal carbenes Isomerization Intramolecular trapping Intermolecular trapping Intermolecular 2+2 cycloaddition Gold(i)-catalyzed synthesis Gold compounds Gold Enantioselective synthesis Cyclopropanation Cycloisomerizations Cycloadditions Cycloaddition process Cycloaddition Cyclization Catalyzed reactions Catalysis Cascade reactions Alkynes 1,6-enynes 1 ,3-dicarbonyl compounds
Resum: The ability of highly energetic metal-carbene intermediates to engage in complex cascade or formal cycloaddition processes is one of the most powerful tools for building intricate molecular architectures in a straightforward manner. Among this type of organometallic intermediates, non-acceptor metal carbenes are particularly challenging to access and, therefore, have experienced slower development. In this regard, our group has exploited the use of electrophilic gold(I) complexes to selectively activate certain classes of substrates for the generation of this type of intermediate. Thus, very different types of molecules, such as enynes or 7-substituted cycloheptatrienes, lead to the formation of carbenes under gold(I) catalysis. Related rhodium(II) carbenes can also be generated from cycloheptatrienes. In this account, we aim to summarize our efforts towards the in situ generation of such highly versatile organometallic species as well as studies on their reactivity through formal cycloadditions or complex cascade reactions.
Àrees temàtiques: Química Organic chemistry Medicina i Materiais Interdisciplinar Farmacia Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, organic Catalysis Biotecnología
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat helena.armengol@estudiants.urv.cat
Identificador de l'autor: 0000-0002-6418-7930
Data d'alta del registre: 2024-07-27
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Synthesis-Stuttgart. 53 (21): 3991-4003
Referència de l'ítem segons les normes APA: Armengol-Relats, Helena; Mato, Mauro; Escofet, Imma; Echavarren, Antonio M.; (2021). Assembling Complex Structures through Cascade and Cycloaddition Processes via Non-Acceptor Gold or Rhodium Carbenes. Synthesis-Stuttgart, 53(21), 3991-4003. DOI: 10.1055/a-1535-3215
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2021
Tipus de publicació: Journal Publications
Repositori URV