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Spectroscopy and efficient laser operation around 2.8 mu m of Er:(Lu,Sc)(2)O-3 sesquioxide ceramics

  • Dades identificatives

    Identificador: imarina:9228568
    Autors:
    Basyrova, LizaLoiko, PavelJing, WeiWang, YichengHuang, HuiDunina, ElenaKornienko, AlexeyFomicheva, LiudmilaViana, BrunoGriebner, UwePetrov, ValentinAguilo, MagdalenaDiaz, FrancescMateos, XavierCamy, Patrice
    Resum:
    A transparent "mixed" 7 at.% Er:(Lu,Sc)(2)O-3 sesquioxide ceramic was fabricated by hot isostatic pressing of commercial sesquioxide powders at 1750 degrees C/200 MPa in argon atmosphere. It exhibited a cubic bixbyite-type structure (a = 10.198 angstrom), a mean grain size of 5.7 um and high low-signal transmission of 79.1 % in the near- IR. The spectroscopic properties of Er3+ ions were studied. For the I-4(11/2) -> I-4(13/2) transition, the stimulated-emission cross-section sigma(SE) is 1.30 x 10(-20) cm(2) at 2719 nm, the corresponding luminescence branching ratio B (JJ') is 19.9 % and the radiative lifetime of the I-4(11/2) state is 4.80 ms, as determined using a Judd-Ofelt theory accounting for intermediate configuration interaction. The crystal-field splitting of Er3+ multiplets was studied at 12 K. The ceramic exhibits a significant inhomogeneous broadening of spectral bands. An Er:(Lu,Sc)(2)O-3 ceramic laser generated 342 mW at 2.71 and 2.85 mu m with a high slope efficiency of 41.7 % (exceeding the Stokes limit) and a laser threshold of 125 mW.
  • Altres:

    Autor segons l'article: Basyrova, Liza; Loiko, Pavel; Jing, Wei; Wang, Yicheng; Huang, Hui; Dunina, Elena; Kornienko, Alexey; Fomicheva, Liudmila; Viana, Bruno; Griebner, Uwe; Petrov, Valentin; Aguilo, Magdalena; Diaz, Francesc; Mateos, Xavier; Camy, Patrice;
    Departament: Química Física i Inorgànica
    Autor/s de la URV: Aguiló Díaz, Magdalena / Díaz Castrillón, Fernanda / Díaz González, Francisco Manuel / Mateos Ferré, Xavier
    Paraules clau: Y2o3 Type structures Transparent ceramics Transparent ceramic Sesquioxides Sesquioxide Sc$-2$/o$-3$ Rare-earth ions Performance Optical-spectra Mean-grain size Luminescence Lu2o3 Laser operations Laser operation Judd-ofelt theory Hot-isostatic pressings Hot isostatic pressing Erlu2o3 Erbium ion Er-yag Energy-levels Crystal-field analysis Continuous-wave Ceramic materials Bixbyite Argon atmospheres
    Resum: A transparent "mixed" 7 at.% Er:(Lu,Sc)(2)O-3 sesquioxide ceramic was fabricated by hot isostatic pressing of commercial sesquioxide powders at 1750 degrees C/200 MPa in argon atmosphere. It exhibited a cubic bixbyite-type structure (a = 10.198 angstrom), a mean grain size of 5.7 um and high low-signal transmission of 79.1 % in the near- IR. The spectroscopic properties of Er3+ ions were studied. For the I-4(11/2) -> I-4(13/2) transition, the stimulated-emission cross-section sigma(SE) is 1.30 x 10(-20) cm(2) at 2719 nm, the corresponding luminescence branching ratio B (JJ') is 19.9 % and the radiative lifetime of the I-4(11/2) state is 4.80 ms, as determined using a Judd-Ofelt theory accounting for intermediate configuration interaction. The crystal-field splitting of Er3+ multiplets was studied at 12 K. The ceramic exhibits a significant inhomogeneous broadening of spectral bands. An Er:(Lu,Sc)(2)O-3 ceramic laser generated 342 mW at 2.71 and 2.85 mu m with a high slope efficiency of 41.7 % (exceeding the Stokes limit) and a laser threshold of 125 mW.
    Àrees temàtiques: Química Optics Odontología Medicina ii Medicina i Materiais Interdisciplinar General chemistry Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Condensed matter physics Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciência de alimentos Chemistry (miscellaneous) Chemistry (all) Biotecnología Biophysics Biochemistry Atomic and molecular physics, and optics Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: f.diaz@urv.cat fernanda.diaz@estudiants.urv.cat magdalena.aguilo@urv.cat xavier.mateos@urv.cat
    Identificador de l'autor: 0000-0003-4581-4967 0000-0001-6130-9579 0000-0003-1940-1990
    Data d'alta del registre: 2024-07-27
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://www.sciencedirect.com/science/article/abs/pii/S0022231321004890
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Journal Of Luminescence. 240
    Referència de l'ítem segons les normes APA: Basyrova, Liza; Loiko, Pavel; Jing, Wei; Wang, Yicheng; Huang, Hui; Dunina, Elena; Kornienko, Alexey; Fomicheva, Liudmila; Viana, Bruno; Griebner, Uwe (2021). Spectroscopy and efficient laser operation around 2.8 mu m of Er:(Lu,Sc)(2)O-3 sesquioxide ceramics. Journal Of Luminescence, 240(), -. DOI: 10.1016/j.jlumin.2021.118373
    DOI de l'article: 10.1016/j.jlumin.2021.118373
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2021
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Atomic and Molecular Physics, and Optics,Biochemistry,Biophysics,Chemistry (Miscellaneous),Condensed Matter Physics,Optics
    Y2o3
    Type structures
    Transparent ceramics
    Transparent ceramic
    Sesquioxides
    Sesquioxide
    Sc$-2$/o$-3$
    Rare-earth ions
    Performance
    Optical-spectra
    Mean-grain size
    Luminescence
    Lu2o3
    Laser operations
    Laser operation
    Judd-ofelt theory
    Hot-isostatic pressings
    Hot isostatic pressing
    Erlu2o3
    Erbium ion
    Er-yag
    Energy-levels
    Crystal-field analysis
    Continuous-wave
    Ceramic materials
    Bixbyite
    Argon atmospheres
    Química
    Optics
    Odontología
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General chemistry
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Condensed matter physics
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciência de alimentos
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Biophysics
    Biochemistry
    Atomic and molecular physics, and optics
    Astronomia / física
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