Articles producció científica> Química Analítica i Química Orgànica

Synthesis and characterization of dendritic compounds containing nitrogen: monomer precursors in the construction of biomimetic membranes

  • Dades identificatives

    Identificador: imarina:9244564
    Autors:
    Guardia, JordiZare, AlirezaEleeza, JohnGiamberini, MartaReina, Jose AntonioMontane, Xavier
    Resum:
    In this article, we synthesized a novel dendritic 2-oxazoline, 2-(3,4,5-tris(4-dodecyloxybenzyloxy)phenyl)-4,5-dihydro-1,3-oxazole), and its amide precursor N-(2-hydroxyethyl)-3,4,5-tris(4-dodecyloxybenzyloxy)benzamide. Of the distinct synthetic routes explored, it was established that the direct amidation of esters with sodium methoxide followed by the dehydrative cyclisation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone as oxidizing agent and triphenylphosphine was the most efficient route to synthesize the dendritic 2-oxazoline. Besides, N-(2-hydroxyethyl)-3,4,5-tris(4-dodecyloxybenzyloxy)benzamide exhibited a monotropic columnar mesophase, whilst the dendritic 2-oxazoline does not exhibited a liquid crystalline mesophase. At the end, the first attempts to polymerize the 2-oxazoline monomer via cationic ring opening polymerization showed promising results. Therefore, the dendritic 2-oxazoline could be used as a mesogenic monomer in the synthesis of side-chain liquid-crystalline polyoxazolines that might self-assembly into columnar structures.© 2022. The Author(s).
  • Altres:

    Autor segons l'article: Guardia, Jordi; Zare, Alireza; Eleeza, John; Giamberini, Marta; Reina, Jose Antonio; Montane, Xavier
    Departament: Química Analítica i Química Orgànica Enginyeria Química
    Autor/s de la URV: Giamberini, Marta / Guardià Blanch, Jordi / Montané Montané, Xavier / Reina Lozano, José Antonio / Zare, Alireza
    Codi de projecte: Grant agreement No. 713679
    Paraules clau: Ion-conducting membranes supramolecular architectures polymerization liquid-crystalline facile synthesis esters design coupling reagents catalyzed amidation 2-oxazolines
    Resum: In this article, we synthesized a novel dendritic 2-oxazoline, 2-(3,4,5-tris(4-dodecyloxybenzyloxy)phenyl)-4,5-dihydro-1,3-oxazole), and its amide precursor N-(2-hydroxyethyl)-3,4,5-tris(4-dodecyloxybenzyloxy)benzamide. Of the distinct synthetic routes explored, it was established that the direct amidation of esters with sodium methoxide followed by the dehydrative cyclisation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone as oxidizing agent and triphenylphosphine was the most efficient route to synthesize the dendritic 2-oxazoline. Besides, N-(2-hydroxyethyl)-3,4,5-tris(4-dodecyloxybenzyloxy)benzamide exhibited a monotropic columnar mesophase, whilst the dendritic 2-oxazoline does not exhibited a liquid crystalline mesophase. At the end, the first attempts to polymerize the 2-oxazoline monomer via cationic ring opening polymerization showed promising results. Therefore, the dendritic 2-oxazoline could be used as a mesogenic monomer in the synthesis of side-chain liquid-crystalline polyoxazolines that might self-assembly into columnar structures.© 2022. The Author(s).
    Àrees temàtiques: Zootecnia / recursos pesqueiros Saúde coletiva Química Psicología Odontología Nutrição Multidisciplinary sciences Multidisciplinary Medicina veterinaria Medicina iii Medicina ii Medicina i Materiais Matemática / probabilidade e estatística Letras / linguística Interdisciplinar Geografía Geociências Farmacia Engenharias iv Engenharias iii Engenharias ii Enfermagem Educação física Educação Economia Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Biotecnología Biodiversidade Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: xavier.montane@urv.cat jordi.guardia@alumni.urv.cat alireza.zare@urv.cat marta.giamberini@urv.cat joseantonio.reina@urv.cat
    Identificador de l'autor: 0000-0002-1426-239X 0000-0003-1345-3140 0000-0002-6981-8914 0000-0001-8278-3552 0000-0002-9245-4135
    Data d'alta del registre: 2024-11-02
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://www.nature.com/articles/s41598-022-05747-1
    Programa de finançament: Marie Skłodowska-Curie Actions - European Union's Horizon 2020 research and innovation program
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Scientific Reports. 12 (1): 1725-1725
    Referència de l'ítem segons les normes APA: Guardia, Jordi; Zare, Alireza; Eleeza, John; Giamberini, Marta; Reina, Jose Antonio; Montane, Xavier (2022). Synthesis and characterization of dendritic compounds containing nitrogen: monomer precursors in the construction of biomimetic membranes. Scientific Reports, 12(1), 1725-1725. DOI: 10.1038/s41598-022-05747-1
    Acrònim: MFP
    DOI de l'article: 10.1038/s41598-022-05747-1
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2022
    Acció del programa de finançament: Martí i Franquès COFUND Doctoral Programme
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Multidisciplinary,Multidisciplinary Sciences
    Ion-conducting membranes
    supramolecular architectures
    polymerization
    liquid-crystalline
    facile synthesis
    esters
    design
    coupling reagents
    catalyzed amidation
    2-oxazolines
    Zootecnia / recursos pesqueiros
    Saúde coletiva
    Química
    Psicología
    Odontología
    Nutrição
    Multidisciplinary sciences
    Multidisciplinary
    Medicina veterinaria
    Medicina iii
    Medicina ii
    Medicina i
    Materiais
    Matemática / probabilidade e estatística
    Letras / linguística
    Interdisciplinar
    Geografía
    Geociências
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Enfermagem
    Educação física
    Educação
    Economia
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Ciência da computação
    Biotecnología
    Biodiversidade
    Astronomia / física
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