Articles producció científica> Enginyeria Química

Dye degradation, antibacterial activity and molecular docking analysis of cellulose/polyvinylpyrrolidone-doped cadmium sulphide quantum dots

  • Dades identificatives

    Identificador: imarina:9267432
    Autors:
    Rafique AIkram MHaider AUl-Hamid ANaz SNabgan WHaider JShahzadi I
    Resum:
    In present study, control sized cadmium sulphide (CdS) quantum dots (QDs) and cellulose nanocrystals grafted polyvinylpyrrolidone (CNC-g-PVP) doped CdS QDs were synthesized via co-precipitation. The suggested pathway is fruitful in throwing out organic pollutants like methylene blue (MB) from industrial water and bactericidal applications. A series of characterization techniques were used to determine the structural, optical and morphological qualities of prepared samples. The X-ray diffraction (XRD) pattern verified hexagonal structure with no significant change occurring in the spectrum upon doping (2, 4, and 6 %). The UV–vis spectrophotometer describes blueshift in absorption pattern, resulting in an increase in band gap energy (Eg) upon doping. Catalytic activity (CA) against MB in basic and neutral medium demonstrated remarkable results compared with the acidic medium. Furthermore, bactericidal potential of doped sample (6 %) exhibited the significantly higher inhibition zones of 5.25 mm and 4.05 mm against Staphylococcus aureus (S. aureus) or Gram-positive (G+ve) and Escherichia coli (E. coli) or Gram-negative (G-ve), respectively. In silico predictions for these doped QDs were performed against selected enzyme targets (i.e. DNA gyrase and FabI) to unveil the mystery governing these bactericidal activities.
  • Altres:

    Autor segons l'article: Rafique A; Ikram M; Haider A; Ul-Hamid A; Naz S; Nabgan W; Haider J; Shahzadi I
    Departament: Enginyeria Química
    Autor/s de la URV: Nabgan, Walid
    Paraules clau: Quantum dots Photocatalytic activity Co-precipitation Catalytic activity removal nanosheets nanoparticles methylene-blue light extract co-precipitation catalytic-reduction catalytic activity biosynthesis
    Resum: In present study, control sized cadmium sulphide (CdS) quantum dots (QDs) and cellulose nanocrystals grafted polyvinylpyrrolidone (CNC-g-PVP) doped CdS QDs were synthesized via co-precipitation. The suggested pathway is fruitful in throwing out organic pollutants like methylene blue (MB) from industrial water and bactericidal applications. A series of characterization techniques were used to determine the structural, optical and morphological qualities of prepared samples. The X-ray diffraction (XRD) pattern verified hexagonal structure with no significant change occurring in the spectrum upon doping (2, 4, and 6 %). The UV–vis spectrophotometer describes blueshift in absorption pattern, resulting in an increase in band gap energy (Eg) upon doping. Catalytic activity (CA) against MB in basic and neutral medium demonstrated remarkable results compared with the acidic medium. Furthermore, bactericidal potential of doped sample (6 %) exhibited the significantly higher inhibition zones of 5.25 mm and 4.05 mm against Staphylococcus aureus (S. aureus) or Gram-positive (G+ve) and Escherichia coli (E. coli) or Gram-negative (G-ve), respectively. In silico predictions for these doped QDs were performed against selected enzyme targets (i.e. DNA gyrase and FabI) to unveil the mystery governing these bactericidal activities.
    Àrees temàtiques: Zootecnia / recursos pesqueiros Structural biology Química Polymer science Planejamento urbano e regional / demografia Odontología Nutrição Molecular biology Medicine (miscellaneous) Medicina veterinaria Medicina iii Medicina ii Medicina i Materiais Interdisciplinar Geociências General energy Food science Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Energy (miscellaneous) Economics and econometrics Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, applied Biotecnología Biomaterials Biodiversidade Biochemistry & molecular biology Biochemistry Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: walid.nabgan@urv.cat
    Identificador de l'autor: 0000-0001-9901-862X
    Data d'alta del registre: 2024-09-07
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://www.sciencedirect.com/science/article/abs/pii/S0141813022012624
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: International Journal Of Biological Macromolecules. 214 264-277
    Referència de l'ítem segons les normes APA: Rafique A; Ikram M; Haider A; Ul-Hamid A; Naz S; Nabgan W; Haider J; Shahzadi I (2022). Dye degradation, antibacterial activity and molecular docking analysis of cellulose/polyvinylpyrrolidone-doped cadmium sulphide quantum dots. International Journal Of Biological Macromolecules, 214(), 264-277. DOI: 10.1016/j.ijbiomac.2022.06.058
    DOI de l'article: 10.1016/j.ijbiomac.2022.06.058
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2022
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Biochemistry,Biochemistry & Molecular Biology,Chemistry, Applied,Economics and Econometrics,Energy (Miscellaneous),Medicine (Miscellaneous),Molecular Biology,Polymer Science,Structural Biology
    Quantum dots
    Photocatalytic activity
    Co-precipitation
    Catalytic activity
    removal
    nanosheets
    nanoparticles
    methylene-blue
    light
    extract
    co-precipitation
    catalytic-reduction
    catalytic activity
    biosynthesis
    Zootecnia / recursos pesqueiros
    Structural biology
    Química
    Polymer science
    Planejamento urbano e regional / demografia
    Odontología
    Nutrição
    Molecular biology
    Medicine (miscellaneous)
    Medicina veterinaria
    Medicina iii
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    Geociências
    General energy
    Food science
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Energy (miscellaneous)
    Economics and econometrics
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, applied
    Biotecnología
    Biomaterials
    Biodiversidade
    Biochemistry & molecular biology
    Biochemistry
    Astronomia / física
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