Autor segons l'article: Diab, Manal; Mateo, Ana; El Cheikh, Joumada; El Hajj, Zeinab; Haouas, Mohamed; Ranjbari, Alireza; Guerineau, Vincent; Touboul, David; Leclerc, Nathalie; Cadot, Emmanuel; Naoufal, Daoud; Bo, Carles; Floquet, Sebastien;
Departament: Química Física i Inorgànica
Autor/s de la URV: Bo Jané, Carles
Resum: Herein we report the synthesis of a new class of compounds associating Keggin and Dawson-type Polyoxometalates (POMs) with a derivative of the anionic decahydro-closo-decaborate cluster [B10H10]2? through aminopropylsilyl ligand (APTES) acting as both a linker and a spacer between the two negatively charged species. Three new adducts were isolated and fully characterized by various NMR techniques and MALDI-TOF mass spectrometry, notably revealing the isolation of an unprecedented monofunctionalized SiW10 derivative stabilized through intramolecular H-H dihydrogen contacts. DFT as well as electrochemical studies allowed studying the electronic effect of grafting the decaborate cluster on the POM moiety and its consequences on the hydrogen evolution reaction (HER) properties.
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Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: carles.bo@urv.cat
Identificador de l'autor: 0000-0001-9581-2922
Data d'alta del registre: 2024-09-07
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://www.mdpi.com/1420-3049/27/22/7663
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Molecules. 27 (22): 7663-
Referència de l'ítem segons les normes APA: Diab, Manal; Mateo, Ana; El Cheikh, Joumada; El Hajj, Zeinab; Haouas, Mohamed; Ranjbari, Alireza; Guerineau, Vincent; Touboul, David; Leclerc, Nathali (2022). Grafting of Anionic Decahydro-Closo-Decaborate Clusters on Keggin and Dawson-Type Polyoxometalates: Syntheses, Studies in Solution, DFT Calculations and Electrochemical Properties. Molecules, 27(22), 7663-. DOI: 10.3390/molecules27227663
DOI de l'article: 10.3390/molecules27227663
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2022
Tipus de publicació: Journal Publications
Repositori URV