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Selective NO2 Gas Sensors Employing Nitrogen- and Boron-Doped and Codoped Reduced Graphene Oxide

  • Dades identificatives

    Identificador: imarina:9385312
    Autors:
    Walleni, ChihebMalik, Shuja BashirMissaoui, GhadaAlouani, Mohamed AyoubNsib, Mohamed FaouziLlobet, Eduard
    Resum:
    In this paper, we develop high-performance gas sensors based on heteroatom-doped and -codoped graphene oxide as a sensing material for the detection of NO2 at trace levels. Graphene oxide (GO) was doped with nitrogen and boron by a chemical method using urea and boric acid as precursors. The prepared samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The obtained results proved the successful reduction of graphene oxide by doping effects, leading to the removal of some oxygen functional groups and restoration of an sp2 carbon structure. New bonds in honeycombs, such as pyridinic, pyrrolic, graphitic, B-C3, B-C2-O, and B-O, were created. Compared to the nondoped GO, the N/B-rGO materials exhibited enhanced responses toward low concentrations of NO2 (
  • Altres:

    Autor segons l'article: Walleni, Chiheb; Malik, Shuja Bashir; Missaoui, Ghada; Alouani, Mohamed Ayoub; Nsib, Mohamed Faouzi; Llobet, Eduard
    Departament: Enginyeria Electrònica, Elèctrica i Automàtica
    Autor/s de la URV: Alouani, Mohamed Ayoub / Llobet Valero, Eduard / Malik, Shuja Bashir
    Paraules clau: Electronic-structure Graphite Humidit Raman-spectroscopy Reduction Sensitivity
    Resum: In this paper, we develop high-performance gas sensors based on heteroatom-doped and -codoped graphene oxide as a sensing material for the detection of NO2 at trace levels. Graphene oxide (GO) was doped with nitrogen and boron by a chemical method using urea and boric acid as precursors. The prepared samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The obtained results proved the successful reduction of graphene oxide by doping effects, leading to the removal of some oxygen functional groups and restoration of an sp2 carbon structure. New bonds in honeycombs, such as pyridinic, pyrrolic, graphitic, B-C3, B-C2-O, and B-O, were created. Compared to the nondoped GO, the N/B-rGO materials exhibited enhanced responses toward low concentrations of NO2 (
    Àrees temàtiques: Chemical engineering (all) Chemical engineering (miscellaneous) Chemistry (all) Chemistry (miscellaneous) Chemistry, multidisciplinary Ciências agrárias i Engenharias ii General chemical engineering General chemistry Interdisciplinar Química
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: eduard.llobet@urv.cat shujabashir.malik@urv.cat mohamedayoub.alouani@urv.cat
    Identificador de l'autor: 0000-0001-6164-4342
    Data d'alta del registre: 2024-10-12
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Referència a l'article segons font original: Acs Omega. 9 (11): 13028-13040
    Referència de l'ítem segons les normes APA: Walleni, Chiheb; Malik, Shuja Bashir; Missaoui, Ghada; Alouani, Mohamed Ayoub; Nsib, Mohamed Faouzi; Llobet, Eduard (2024). Selective NO2 Gas Sensors Employing Nitrogen- and Boron-Doped and Codoped Reduced Graphene Oxide. Acs Omega, 9(11), 13028-13040. DOI: 10.1021/acsomega.3c09460
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2024
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Chemical Engineering (Miscellaneous),Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Electronic-structure
    Graphite
    Humidit
    Raman-spectroscopy
    Reduction
    Sensitivity
    Chemical engineering (all)
    Chemical engineering (miscellaneous)
    Chemistry (all)
    Chemistry (miscellaneous)
    Chemistry, multidisciplinary
    Ciências agrárias i
    Engenharias ii
    General chemical engineering
    General chemistry
    Interdisciplinar
    Química
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