Fluoride Clusterfullerenes: Tuning Metal-Metal Bonding and Magnetic Properties via Single Fluorine Atom Doping

Identificador:  imarina:9407086

Handle: https://hdl.handle.net/20.500.11797/imarina9407086

Autors:  Shen, Y; Roselló, Y; Abella, L; Qiu, JW; Du, XY; Meng, QY; Zheng, LH; Cao, ZK; He, ZW; Poblet, JM; Echegoyen, L; Sun, L; Rodríguez-Fortea, A; Chen, N

Resum:
Endohedral fullerenes are known for their exceptional ability to host metal clusters that contain unique bonding motifs. In this study, we report a facile strategy to synthesize a new family of clusterfullerenes, fluoride clusterfullerenes (FCFs). This work demonstrates that actinides and rare earth metals as well as alkaline earth metals can be encapsulated within a variety of fullerene cages, and these fullerenes can be obtained in their pristine form without additional functionalization methods. Notably, Th2F@I h(7)-C80 and CaScF@C s(6)-C82 were isolated and their molecular structures and magnetic properties were characterized by X-ray single-crystal diffraction and multiple spectroscopic techniques as well as DFT calculations. These findings reveal that the unique internal addition of a single fluorine atom significantly alters the metal-metal bonding interactions of Th-Th and Ca-Sc. While Th2@I h(7)-C80 hosts a sigma 2 Th-Th bond, an unprecedented actinide-actinide (Th-Th) single electron metal-metal bond is formed inside Th2F@I h(7)-C80 upon the internal addition of fluoride. Similarly, while a Ca-Sc single electron bond exists in CaSc@C s(6)-C82, which exhibits excellent molecular qubit properties, the addition of fluoride transforms the compound into a singlet. The present study not only highlights the successful synthesis of a novel family of FCFs, which will likely be an extensive family, it also shows that fluorine doping can induce novel metal-metal bonding motifs leading to potentially intriguing magnetic properties.