Author, as appears in the article.: M. Isabel Matheu Joan Guasch Yolanda Díaz Sergio Castillón
Department: Química Analítica i Química Orgànica
URV's Author/s: MATHEU MALPARTIDA, MARÍA ISABEL Joan Guasch Yolanda Díaz Sergio Castillón
Keywords: intramolecular aziridination
Abstract: The reaction of dienyl carbamates with PhI(OR)2 in the presence of rhodium catalysts affords vinyl aziridines which are in situ regio- and stereoselectively opened to afford oxyamination products resulting from a selective SN2 (Rh2(OAc)4/PhI(OPiv)2) or SN20 (Rh2(OPiv)4/PhI(OAc)2) opening. The scope and limitations of this tandem process are described.
Research group: Síntesis Orgànica Estereoselectiva
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1359-7345
Author identifier: 0000-0001-5216-9260 n/a 0000-0001-5567-8108 n/a
Record's date: 2015-04-16
Last page: 7347
Journal volume: 50
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2014
First page: 7344
Publication Type: Article Artículo Article
Repositori URV