Articles producció científicaQuímica Analítica i Química Orgànica

Rhodium-catalyzed regio- and stereoselective oxyamination of dienes via tandem aziridination/ ring-opening of dienyl carbamates

  • Identification data

    Identifier:  PC:1157
    Handle: https://hdl.handle.net/20.500.11797/PC1157
    Authors:  M. Isabel Matheu; Joan Guasch; Yolanda Díaz; Sergio Castillón
    Abstract:
    The reaction of dienyl carbamates with PhI(OR)2 in the presence of rhodium catalysts affords vinyl aziridines which are in situ regio- and stereoselectively opened to afford oxyamination products resulting from a selective SN2 (Rh2(OAc)4/PhI(OPiv)2) or SN20 (Rh2(OPiv)4/PhI(OAc)2) opening. The scope and limitations of this tandem process are described.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc01312c#!divAbstract
    Article's DOI: 10.1039/c4cc01312c
    Journal publication year: 2014
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2015-04-16
    First page: 7344
    URV's Author/s: MATHEU MALPARTIDA, MARÍA ISABEL, Joan Guasch, Yolanda Díaz, Sergio Castillón
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Article
    Last page: 7347
    ISSN: 1359-7345
    Author, as appears in the article.: M. Isabel Matheu, Joan Guasch, Yolanda Díaz, Sergio Castillón
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Journal volume: 50
    Research group: Síntesis Orgànica Estereoselectiva
    Thematic Areas: Chemistry