Articles producció científica> Química Analítica i Química Orgànica

Rhodium-catalyzed regio- and stereoselective oxyamination of dienes via tandem aziridination/ ring-opening of dienyl carbamates

  • Identification data

    Identifier: PC:1157
    Authors:
    M. Isabel MatheuJoan GuaschYolanda DíazSergio Castillón
    Abstract:
    The reaction of dienyl carbamates with PhI(OR)2 in the presence of rhodium catalysts affords vinyl aziridines which are in situ regio- and stereoselectively opened to afford oxyamination products resulting from a selective SN2 (Rh2(OAc)4/PhI(OPiv)2) or SN20 (Rh2(OPiv)4/PhI(OAc)2) opening. The scope and limitations of this tandem process are described.
  • Others:

    Author, as appears in the article.: M. Isabel Matheu Joan Guasch Yolanda Díaz Sergio Castillón
    Department: Química Analítica i Química Orgànica
    URV's Author/s: MATHEU MALPARTIDA, MARÍA ISABEL Joan Guasch Yolanda Díaz Sergio Castillón
    Keywords: intramolecular aziridination
    Abstract: The reaction of dienyl carbamates with PhI(OR)2 in the presence of rhodium catalysts affords vinyl aziridines which are in situ regio- and stereoselectively opened to afford oxyamination products resulting from a selective SN2 (Rh2(OAc)4/PhI(OPiv)2) or SN20 (Rh2(OPiv)4/PhI(OAc)2) opening. The scope and limitations of this tandem process are described.
    Research group: Síntesis Orgànica Estereoselectiva
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1359-7345
    Author identifier: 0000-0001-5216-9260 n/a 0000-0001-5567-8108 n/a
    Record's date: 2015-04-16
    Last page: 7347
    Journal volume: 50
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc01312c#!divAbstract
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1039/c4cc01312c
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2014
    First page: 7344
    Publication Type: Article Artículo Article
  • Keywords:

    Estereoquímica
    Rodi - Catàlisi
    Reaccions químiques
    intramolecular aziridination
    Química
    Química
    Chemistry
    1359-7345
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