Author, as appears in the article.: Michael E. Muratore Yahui Wang Antonio M. Echavarren
Department: Química Analítica i Química Orgànica
URV's Author/s: Michael E. Muratore Yahui Wang ECHAVARREN PABLOS, ANTONIO MARIA
Keywords: Carbenoids Carbenes Back donation
Abstract: Abstract By reviewing the recent progress on the elucidation of the structure of gold carbenes and the definitions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or carbocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene ¿-back-donation and their strongly electrophilic reactivity, could be classified into the broader family of Fischer carbenes, although their behavior and properties are very specific. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thematic Areas: Chemistry Química Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0947-6539
Author identifier: n/a n/a 0000-0001-6808-3007
Record's date: 2015-07-31
Last page: 7339
Journal volume: 21
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/chem.201406318/full
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1002/chem.201406318
Entity: Universitat Rovira i Virgili
Journal publication year: 2015
First page: 7332
Publication Type: Article Artículo Article
Repositori URV