Articles producció científica> Química Física i Inorgànica

Stereospecific SN2@P reactions: novel access to bulky P-stereogenic ligands

  • Identification data

    Identifier: PC:1249
    Authors:
    Oscar PàmiesSílvia OrgueAreli Flores-GasparMaria BioscaMontserrat DiéguezAntoni RieraXavier Verdaguer
    Abstract:
    The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.
  • Others:

    Author, as appears in the article.: Oscar Pàmies Sílvia Orgue Areli Flores-Gaspar Maria Biosca Montserrat Diéguez Antoni Riera Xavier Verdaguer
    Department: Química Física i Inorgànica
    URV's Author/s: PAMIES OLLÉ, OSCAR Sílvia Orgue Areli Flores-Gaspar Maria Biosca DIÉGUEZ FERNÁNDEZ, MONTSERRAT Antoni Riera Xavier Verdaguer
    Keywords: asymmetric catalysis P*-ligands
    Abstract: The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1359-7345
    Author identifier: 0000-0002-2352-8508 n/a n/a n/a 0000-0002-8450-0656 0000-0001-7142-7675 0000-0002-9229-969X
    Record's date: 2015-10-30
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2015/CC/C5CC07504A#!divAbstract
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1039/c5cc07504a
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2015
    Publication Type: Article Artículo Article
  • Keywords:

    Catàlisi asimètrica
    Lligands
    asymmetric catalysis
    P*-ligands
    Química
    Química
    Chemistry
    1359-7345
  • Documents:

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