Author, as appears in the article.: Oscar Pàmies Sílvia Orgue Areli Flores-Gaspar Maria Biosca Montserrat Diéguez Antoni Riera Xavier Verdaguer
Department: Química Física i Inorgànica
URV's Author/s: PAMIES OLLÉ, OSCAR Sílvia Orgue Areli Flores-Gaspar Maria Biosca DIÉGUEZ FERNÁNDEZ, MONTSERRAT Antoni Riera Xavier Verdaguer
Keywords: asymmetric catalysis P*-ligands
Abstract: The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1359-7345
Author identifier: 0000-0002-2352-8508 n/a n/a n/a 0000-0002-8450-0656 0000-0001-7142-7675 0000-0002-9229-969X
Record's date: 2015-10-30
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2015/CC/C5CC07504A#!divAbstract
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1039/c5cc07504a
Entity: Universitat Rovira i Virgili
Journal publication year: 2015
Publication Type: Article Artículo Article