Articles producció científicaQuímica Física i Inorgànica

Stereospecific SN2@P reactions: novel access to bulky P-stereogenic ligands

  • Identification data

    Identifier:  PC:1249
    Handle: https://hdl.handle.net/20.500.11797/PC1249
    Authors:  Oscar Pàmies; Sílvia Orgue; Areli Flores-Gaspar; Maria Biosca; Montserrat Diéguez; Antoni Riera; Xavier Verdaguer
    Abstract:
    The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2015/CC/C5CC07504A#!divAbstract
    Article's DOI: 10.1039/c5cc07504a
    Journal publication year: 2015
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2015-10-30
    URV's Author/s: PAMIES OLLÉ, OSCAR, Sílvia Orgue, Areli Flores-Gaspar, Maria Biosca, DIÉGUEZ FERNÁNDEZ, MONTSERRAT, Antoni Riera, Xavier Verdaguer
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Article
    ISSN: 1359-7345
    Author, as appears in the article.: Oscar Pàmies, Sílvia Orgue, Areli Flores-Gaspar, Maria Biosca, Montserrat Diéguez, Antoni Riera, Xavier Verdaguer
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Chemistry

  • Keywords:

    asymmetric catalysis
    P*-ligands

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