Author, as appears in the article.: Antonio M. Echavarren; Mariia S. Kirillova; Michael E. Muratore; Ruth Dorel
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO MARIA; Mariia S. Kirillova; Michael E. Muratore; Ruth Dorel
Keywords: Synthesis (chemical) Gold catalysis
Abstract: The total synthesis of lundurines A-C has been accomplished in racemic and enantiopure forms in 11-13 and 12-14 steps, respectively, without protection/deprotection of functional groups, by a novel tandem double condensation/Claisen rearrangement, a gold(I)-catalyzed alkyne hydroarylation, a cyclopropanation via formal [3 + 2] cycloaddition/nitrogen extrusion, and a remarkable olefin migration through a vinylcyclopropane retro-ene/ene reaction that streamlines the endgame.
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0002-7863
Author identifier: 0000-0001-6808-3007; n/a; n/a; n/a
Record's date: 2016-05-02
Last page: 3674
Journal volume: 138
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/jacs.6b01428
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1021/jacs.6b01428
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
First page: 3671
Publication Type: Article Artículo Article
Repositori URV