Articles producció científicaQuímica Analítica i Química Orgànica

Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition

  • Identification data

    Identifier:  PC:1534
    Handle: https://hdl.handle.net/20.500.11797/PC1534
    Authors:  Antonio M. Echavarren; Beatrice Ranieri; Carla Obradors; Mauro Mato
    Abstract:
    The enantioselective total synthesis of rumphellaone A has been accomplished in 12 steps via a diastereoselective gold(I)-catalyzed [2 + 2] macrocyclization of a 1,10-enyne as the key step to build the cyclobutene moiety. This concise approach has also led to the total synthesis of husinone.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acs.orglett.6b00473
    Article's DOI: 10.1021/acs.orglett.6b00473
    Journal publication year: 2016
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2016-05-10
    First page: 1614
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO MARIA; Beatrice Ranieri; Carla Obradors; Mauro Mato
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Article
    Last page: 1617
    ISSN: 1523-7060
    Author, as appears in the article.: Antonio M. Echavarren; Beatrice Ranieri; Carla Obradors; Mauro Mato
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Journal volume: 18
    Thematic Areas: Chemistry