Author, as appears in the article.: Marc G. Civit; Jordi Royes; Christopher M. Vogels; Stephen A. Westcott; Ana B. Cuenca; Elena Fernández
Department: Química Física i Inorgànica
URV's Author/s: GARCIA CIVIT, MARC; Jordi Royes; Christopher M. Vogels; Stephen A. Westcott; Ana B. Cuenca; Elena Fernández
Keywords: Reagents pinB-SR Alkyls Post-translational modification
Abstract: The insertion of the diazo derivative Me3SiCHN2 into pinB-SR ¿ bonds (R = Ph, Tol, Bn) allows a direct synthesis of multisubstituted H-C(SR)(Bpin)(SiMe3) compounds. Consecutive base-assisted transformations of HC(S)(B) (Si) systems lead to deborylative alkylations, Sommelet-Haüser rearrangements, and deprotoalkylations. Intramolecular cyclizations can be selectively performed either via desilylative or deborylative manifolds by fine-tuning the base employed.
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1523-7060
Author identifier: 0000-0002-1012-3739; 0000-0001-6129-7344; N/A; 0000-0002-5324-2295; 0000-0002-6842-1261; 0000-0001-9025-1791
Record's date: 2016-09-21
Last page: 3833
Journal volume: 18
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b01840
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1021/acs.orglett.6b01840
Entity: Universitat Rovira i Virgili
Journal publication year: 2015
First page: 3830
Publication Type: Article Artículo Article
Repositori URV