Articles producció científica> Química Física i Inorgànica

Highly versatile Pd-thioether-phosphite catalytic systems for asymmetric allylic alkylation, amination, and etherification reactions

  • Identification data

    Identifier: PC:2565
    Authors:
    Mercè CollOscar PàmiesMontserrat Diéguez
    Abstract:
    Filiació URV: SIInclòs a la memòria: SI
  • Others:

    Author, as appears in the article.: Mercè Coll; Oscar Pàmies; Montserrat Diéguez
    Department: Química Física i Inorgànica
    URV's Author/s: COLL SERRAHIMA, MARIA MERCÈ; PAMIES OLLÉ, OSCAR; DIÉGUEZ FERNÁNDEZ, MONTSERRAT
    Keywords: palladium allylic substitution phosphite-thioether ligands
    Abstract: A Pd-furanoside thioether-phosphite catalytic system that can create new C-C, C-N, and C-O bonds in several substrate types using a wide range of nucleophiles in high yields and enantioselectivities has been identified. Of particular note are the excellent enantioselectivities obtained in the etherification of linear and cyclic substrates. The potential application of the new Pd-thioether-phosphite catalytic systems was also demonstrated by the synthesis of the chiral carbo- and heterocycles.
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1523-7060
    Author identifier: n/a; 0000-0002-2352-8508; 0000-0002-8450-0656
    Record's date: 2017-02-22
    Last page: 1895
    Journal volume: 16
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://pubs.acs.org/doi/10.1021/ol500758y
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1021/ol500758y
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2014
    First page: 1892
    Publication Type: Post-print
  • Keywords:

    Catàlisi asimètrica
    Pal·ladi (Element químic) -- Catàlisi
    Allylation
    palladium
    allylic substitution
    phosphite-thioether ligands
    Química
    Química
    Chemistry
    1523-7060
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