Author, as appears in the article.: Mercè Coll; Oscar Pàmies; Montserrat Diéguez
Department: Química Física i Inorgànica
URV's Author/s: COLL SERRAHIMA, MARIA MERCÈ; PAMIES OLLÉ, OSCAR; DIÉGUEZ FERNÁNDEZ, MONTSERRAT
Keywords: palladium allylic substitution phosphite-thioether ligands
Abstract: A Pd-furanoside thioether-phosphite catalytic system that can create new C-C, C-N, and C-O bonds in several substrate types using a wide range of nucleophiles in high yields and enantioselectivities has been identified. Of particular note are the excellent enantioselectivities obtained in the etherification of linear and cyclic substrates. The potential application of the new Pd-thioether-phosphite catalytic systems was also demonstrated by the synthesis of the chiral carbo- and heterocycles.
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1523-7060
Author identifier: n/a; 0000-0002-2352-8508; 0000-0002-8450-0656
Record's date: 2017-02-22
Last page: 1895
Journal volume: 16
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/ol500758y
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1021/ol500758y
Entity: Universitat Rovira i Virgili
Journal publication year: 2014
First page: 1892
Publication Type: Post-print