Articles producció científica> Química Física i Inorgànica

Asymmetric metal free β-boration of α,β-unsaturated imines assisted by (S)-MeBoPhoz

  • Identification data

    Identifier: PC:2618
    Authors:
    Sanz, X.Cascia, E.L.Bo, C.Whiting, A.Fernandez, E.
    Abstract:
    author can archive pre-print (ie pre-refereeing) 12 meses de embargo DOI: 10.1039/c4ob02478h URL: http://pubs.rsc.org/en/Content/ArticleLanding/2015/OB/C4OB02478H#!divAbstract Filiació URV: SI
  • Others:

    Author, as appears in the article.: Sanz, X.; Cascia, E.L.; Bo, C.; Whiting, A.; Fernandez, E.
    Department: Química Física i Inorgànica
    URV's Author/s: SANZ LÓPEZ, XAVIER; Cascia, E.L.; Bo, C.; Whiting, A.; FERNÁNDEZ GUTIÉRREZ, MARIA ELENA
    Keywords: beta-boration
    Abstract: The adduct [MeO ¿ Bpin-Bpin]- efficiently mediates the ¿-boration of ¿,¿-unsaturated imines formed in situ. The use of chiral phosphines as additives, and in particular the chiral phosphine (S)-MeBoPhoz, enables the catalytic asymmetric reaction to proceed with higher enantioselectivity than the analogue copper(i) mediated reaction.
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1477-0520
    Author identifier: 0000-0003-0322-6796; n/a; n/a; n/a; 0000-0001-9025-1791
    Record's date: 2017-03-16
    Last page: 1332
    Journal volume: 13
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2015/OB/C4OB02478H#!divAbstract
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1039/C4OB02478H
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2015
    First page: 1328
    Publication Type: Article Artículo Article
  • Keywords:

    Compostos organometàl·lics
    Catàlisi homogènia
    beta-boration
    Química
    Química
    Chemistry
    1477-0520
  • Documents:

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