Articles producció científicaQuímica Física i Inorgànica

Asymmetric metal free ¿-boration of ¿

  • Identification data

    Identifier:  PC:2618
    Handle: https://hdl.handle.net/20.500.11797/PC2618
    Authors:  Sanz, X.; Cascia, E.L.; Bo, C.; Whiting, A.; Fernandez, E.
    Abstract:
    The adduct [MeO ¿ Bpin-Bpin]- efficiently mediates the ¿-boration of ¿,¿-unsaturated imines formed in situ. The use of chiral phosphines as additives, and in particular the chiral phosphine (S)-MeBoPhoz, enables the catalytic asymmetric reaction to proceed with higher enantioselectivity than the analogue copper(i) mediated reaction.

  • Others:

    Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2015/OB/C4OB02478H#!divAbstract
    Article's DOI: 10.1039/C4OB02478H
    Journal publication year: 2015
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2017-03-16
    First page: 1328
    URV's Author/s: SANZ LÓPEZ, XAVIER; Cascia, E.L.; Bo, C.; Whiting, A.; FERNÁNDEZ GUTIÉRREZ, MARIA ELENA
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Article
    Last page: 1332
    ISSN: 1477-0520
    Author, as appears in the article.: Sanz, X.; Cascia, E.L.; Bo, C.; Whiting, A.; Fernandez, E.
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Journal volume: 13
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Chemistry