Author, as appears in the article.: Claver, C.; Mercadé, E.; Zangrando, E.; Godard, C.
Department: Química Física i Inorgànica
URV's Author/s: CLAVER CABRERO, MARIA DEL CARMEN OROSIA; Mercadé, E.; Zangrando, E.; GODARD ., CYRIL
Keywords: polycarbonates
Abstract: New zinc catalysts bearing the ligands 1-4 containing a pyrrolidine scaffold were synthesized and successfully tested in the coupling of CO2 with terminal and internal epoxides, providing excellent activity and total selectivity to the corresponding cyclic carbonates, even for challenging substrates such as cyclohexene oxide, trans-1,2-epoxybutane and methyl epoxioleate. The Zn-3/TBAI catalytic system revealed as the most active of the series and its robustness was demonstrated through TON values up to 1840 for propylene oxide. The recycling of this catalytic system was also performed up to 5 times without relevant loss of activity using this substrate
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1867-3880
Author identifier: 0000-0002-2518-7401; n/a; 0000-0003-1549-4560; 0000-0001-5762-4904
Record's date: 2017-03-22
Last page: 243
Journal volume: 8
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
First page: 234
Publication Type: Article Artículo Article
Repositori URV