Author, as appears in the article.: Castillón, S.; Delgado, J.A.; Curulla-Ferré, D.; Claver, C.; Godard, C.
Department: Química Física i Inorgànica Química Analítica i Química Orgànica
URV's Author/s: CASTILLÓN MIRANDA, SERGIO; Delgado, J.A.; Curulla-Ferré, D.; CLAVER CABRERO, MARIA DEL CARMEN OROSIA; GODARD ., CYRIL
Keywords: pH effect Fischer-Tropsch cobalt nanoparticles
Abstract: Cobalt nanoparticles of 2.6 nm were synthesized in water using NaBH4 as the reducing agent and PVP as stabilizer. The nanoparticles were fully characterized and their catalytic performances evaluated in the aqueous phase Fischer-Tropsch Synthesis (AFTS) at various pH values. The pH of the catalytic solution was shown to affect both the activity and selectivity of the AFTS reaction since side reactions such as WGS and formation of formate from CO2 were favored at basic pH.
Research group: Síntesis Orgànica Estereoselectiva Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Chemistry Química Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1566-7367
Author identifier: 0000-0002-0690-7549; n/a; n/a; 0000-0002-2518-7401; 0000-0001-5762-4904
Record's date: 2017-03-22
Last page: 92
Journal volume: 71
Papper version: info:eu-repo/semantics/submittedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1016/j.catcom.2015.08.003
Entity: Universitat Rovira i Virgili
Journal publication year: 2015
First page: 88
Publication Type: Article Artículo Article
Repositori URV