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Fischer-Tropsch synthesis catalysed by small TiO2 supported cobalt nanoparticles prepared by sodium borohydride reduction

  • Identification data

    Identifier: PC:2699
    Authors:
    Claver, C.Delgado, J.A.Castillón, S.Curulla-Ferré, D.Ordomsky, V.V.Godard, C.
    Abstract:
    author can archive pre-print (ie pre-refereeing) El título original que se cambio por sugerencia de los referees es el que consta en el pre print Remarkable Stability of Small Cobalt NanoparticlesPrepared by Sodium Borohydride Reduction in the Fischer-Tropsch Synthesis
  • Others:

    Author, as appears in the article.: Claver, C.; Delgado, J.A.; Castillón, S.; Curulla-Ferré, D.; Ordomsky, V.V.; Godard, C.
    Department: Química Física i Inorgànica Química Analítica i Química Orgànica
    URV's Author/s: CLAVER CABRERO, MARIA DEL CARMEN OROSIA; Delgado, J.A.; CASTILLÓN MIRANDA, SERGIO; Curulla-Ferré, D.; Ordomsky, V.V.; GODARD ., CYRIL
    Keywords: Fischer-Tropsch synthesis cobalt nanoparticles Titanium Oxide
    Abstract: tCobalt nanoparticles in the range of 1.7¿7 nm were synthesized in water using sodium borohydride asreducing agent and subsequently immobilized on TiO2. Both colloidal and TiO2supported NPs were char-acterized by TEM, XRD, HRTEM, XPS, TGA, ICP techniques and their catalytic performance of the supportedcatalysts evaluated in the Fischer¿Tropsch synthesis. As a general trend, an increase in activity and TOFwas observed when the particle size decreased. These results were rationalized by the higher reducibilityof the catalysts bearing the smaller nanoparticles. The unconventional stability of these relatively smallCoNPs in FTS was attributed to the promoting effect of boron on the stability of the cobalt nanocrystals
    Research group: Organometàl.lics i Catàlisi Homogènia Síntesis Orgànica Estereoselectiva
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 0926-860X
    Author identifier: ; 0000-0002-8534-3090; ; 0000-0002-9001-7425; n/a;
    Record's date: 2017-03-22
    Last page: 46
    Journal volume: 513
    Papper version: info:eu-repo/semantics/submittedVersion
    Link to the original source: http://www.sciencedirect.com/science/article/pii/S0926860X15302933?via%3Dihub
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1016/j.apcata.2015.12.019
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2015
    First page: 39
    Publication Type: Article Artículo Article
  • Keywords:

    Cobalt -- Nanopartícules
    Fischer-Tropsch, Procediment de
    Fischer-Tropsch synthesis
    cobalt nanoparticles
    Titanium Oxide
    Química
    Química
    Chemistry
    0926-860X
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