Author, as appears in the article.: Echavarren, A.M.; Rong, Z.
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO MARIA; Rong, Z.
Keywords: cyclization catalysis
Abstract: The polycyclisation of polyenynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon-carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings. In addition to terminal alkynes, bromoalkynes can also be used as initiators of polyene cyclisations, giving rise to synthetically useful cyclic bromoalkenes.
Thematic Areas: Chemistry Química Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1477-0520
Author identifier: ; n/a
Record's date: 2017-03-28
Last page: 2167
Journal volume: 15
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2017/OB/C7OB00235A#!divAbstract
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1039/c7ob00235a
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
First page: 2163
Publication Type: Article Artículo Article
Repositori URV