Articles producció científica> Química Física i Inorgànica

Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes 

  • Identification data

    Identifier: PC:3111
    Authors:
    Claver, C.Díaz de los Bernardos, M.Pérez-Rodríguez, S.Gual, A.Godard, C.
    Abstract:
    Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities
  • Others:

    Author, as appears in the article.: Claver, C. ; Díaz de los Bernardos, M. ; Pérez-Rodríguez, S. ; Gual, A. ; Godard, C.
    Department: Química Física i Inorgànica
    Acronym 2: ECO2VALCAT
    URV's Author/s: CLAVER CABRERO, MARIA DEL CARMEN OROSIA; Díaz de los Bernardos, M. ; Pérez-Rodríguez, S. ; Gual, A. ; GODARD , CYRIL
    Abstract: Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities
    Program founding action 2: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Chemistry Química Química
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1359-7345
    Author identifier: 0000-0002-2518-7401; ; ; ; 0000-0001-5762-4904
    Record's date: 2018-02-20
    Project code 2: CTQ2016-75016-R
    Journal volume: 53
    Founding program 2: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2017/CC/C7CC01779K#!divAbstract
    Funding program: european; TERRA; 677471 plan; Retos; CTQ2016-75016-R, AEI/FEDER, UE)
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1039/c7cc01779k
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    First page: 7894
    Publication Type: Article Artículo Article
  • Keywords:

    Hidrogenació
    Alquins
    Nanopartícules
    Chemistry
    Química
    Química
    1359-7345
  • Documents:

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