Articles producció científica> Química Física i Inorgànica

Synthesis of a naphthodiazaborole and its verification by planarization with AFM

  • Identification data

    Identifier: PC:3177
    Authors:
    Fernández, E.Majzik, ZCuenca, A. B.Pavlicek, N.Miralles, N.Meyer, G.Gross, L.
    Abstract:
    Aiming to develop materials with new functionalities, we designed the synthesis of a naphthodiazaborinine (the BN isoster of the phenalenyl anion) that is bonded to a hindered di-orthosubstituted aryl system (9-anthracene). We used atomic force microscopy (AFM) to verify the structure of the molecule synthesized. To determine it unambiguously, we planarized the originally nonplanar molecule by removing H atoms that cause steric hindrance.
  • Others:

    Author, as appears in the article.: Fernández, E. ; Majzik, Z ; Cuenca, A. B. ; Pavlicek, N. ; Miralles, N. ; Meyer, G. ; Gross, L.
    Department: Química Física i Inorgànica
    URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Majzik, Z ; Cuenca, A. B. ; Pavlicek, N. ; Miralles, N. ; Meyer, G. ; Gross, L.
    Keywords: Bdan AFM STM
    Abstract: Aiming to develop materials with new functionalities, we designed the synthesis of a naphthodiazaborinine (the BN isoster of the phenalenyl anion) that is bonded to a hindered di-orthosubstituted aryl system (9-anthracene). We used atomic force microscopy (AFM) to verify the structure of the molecule synthesized. To determine it unambiguously, we planarized the originally nonplanar molecule by removing H atoms that cause steric hindrance.
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1936-0851
    Author identifier: 0000-0001-9025-1791; ; ; ; 0000-0001-8598-0252; ;
    Record's date: 2018-03-08
    Last page: 5345
    Journal volume: 10
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://pubs.acs.org/doi/10.1021/acsnano.6b01484
    Funding program: european; European Research Council Advanced Grant; CEMAS; 291194 european; European Union project; PAMS; 610446 european; Initial Training Network¿s; QTea; 317485 plan; Excelencia; CTQ2013- 43395P plan; Explora; CTQ2013-50219-EXP
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1021/acsnano.6b01484
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    First page: 5340
    Publication Type: Article Artículo Article
  • Keywords:

    Funcional de densitat, Teoria del
    Bdan
    AFM
    STM
    Química
    Química
    Chemistry
    1936-0851
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