Author, as appears in the article.: Fernández, E. ; Miralles, N. ; Gómez, J. E. ; Kleij, A.
Department: Química Física i Inorgànica
URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Miralles, N. ; Gómez, J. E. ; Kleij, A.
Keywords: Copper-Mediated SN2 Allyl Boryl Coupling Allyl Alkyl coupling
Abstract: A method for the copper-catalyzed borylmethylation and borylation of vinyl cyclic carbonates through an SN2¿ mechanism is reported. These singular reactions involve selective SN2¿ allylic substitutions with concomitant ring opening of the cyclic carbonate, and with extrusion of CO2 and formation of a useful hydroxyl functionality in a single step. The stereoselectivity of the homoallylic borylation and allylic borylation processes can be controlled, and synthetically useful unsaturated (E)-pent-2-ene-1,5-diols and (E)-but-2-ene-1,4-diols accessed
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1523-7060
Author identifier: 0000-0001-9025-1791; ; ;
Record's date: 2018-03-08
Last page: 6099
Journal volume: 19
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://pubs-acs-org.sabidi.urv.cat/doi/abs/10.1021/acs.orglett.7b02947
Funding program: plan; Excelencia; CTQ2016-80328-P plan; CTQ-2014¿60419-R altres; Severo Ochoa Excellence Accreditation 2014¿2018 ; SEV-2013¿0319
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1021/acs.orglett.7b02947
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
First page: 6096
Publication Type: Article Artículo Article
Repositori URV