Articles producció científica> Química Física i Inorgànica

Reactivity differences of Sc3N@C2n (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D5h-C80

  • Identification data

    Identifier: PC:3383
    Authors:
    Rodriguez-Fortea, AMaria R. cerónMarta IzquierdoNúria AlegretJuan A. ValdezMarilyn M. OlmsteadAlan L. BalchPoblet, JMLuis Echegoyen
    Abstract:
    Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@Ih-C80 and Sc3N@D3h-C78 and a mixture of Sc3N@D5h-C80 and Sc3N@D3-C68. Taking advantage of their chemical reactivity differences, Sc3N@D5h-C80 was isolated from Sc3N@D3-C68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D5h-C80.
  • Others:

    Author, as appears in the article.: Rodriguez-Fortea, A; Maria R. cerón; Marta Izquierdo; Núria Alegret; Juan A. Valdez; Marilyn M. Olmstead; Alan L. Balch; Poblet, JM; Luis Echegoyen
    Department: Química Física i Inorgànica
    URV's Author/s: RODRÍGUEZ FORTEA, ANTONIO; Maria R. cerón; Marta Izquierdo; Núria Alegret; Juan A. Valdez; Marilyn M. Olmstead; Alan L. Balch; POBLET RIUS, JOSEP MARIA; Luis Echegoyen
    Abstract: Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@Ih-C80 and Sc3N@D3h-C78 and a mixture of Sc3N@D5h-C80 and Sc3N@D3-C68. Taking advantage of their chemical reactivity differences, Sc3N@D5h-C80 was isolated from Sc3N@D3-C68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D5h-C80.
    Research group: Química Quàntica
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1359-7345
    Author identifier: 0000-0001-5884-5629; ; ; ; ; ; ; 0000-0002-4533-0623;
    Record's date: 2019-01-14
    Last page: 67
    Journal volume: 52
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2016/CC/C5CC07416A#!divAbstract
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1039/c5cc07416a
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2015
    First page: 64
    Publication Type: Article Artículo Article
  • Keywords:

    Ful·lerens
    Isomeria
    Química
    Química
    Chemistry
    1359-7345
  • Documents:

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