Author, as appears in the article.: La Cascia, Enrico; Sanz, Xavier; Bo, Carles; Whiting, Andrew; Fernandez, Elena;
Department: Química Física i Inorgànica
URV's Author/s: Bo Jané, Carles / Fernández Gutiérrez, Maria Elena / SANZ LÓPEZ, XAVIER
Keywords: Beta-boration
Abstract: The adduct [MeO → Bpin-Bpin]- efficiently mediates the β-boration of α,β-unsaturated imines formed in situ. The use of chiral phosphines as additives, and in particular the chiral phosphine (S)-MeBoPhoz, enables the catalytic asymmetric reaction to proceed with higher enantioselectivity than the analogue copper(i) mediated reaction.
Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Odontología Medicina ii Medicina i Materiais Interdisciplinar General medicine Farmacia Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, organic Biotecnología Biodiversidade Biochemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: carles.bo@urv.cat mariaelena.fernandez@urv.cat
Author identifier: 0000-0001-9581-2922 0000-0001-9025-1791
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2015/ob/c4ob02478h
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Organic & Biomolecular Chemistry. 13 (5): 1328-1332
APA: La Cascia, Enrico; Sanz, Xavier; Bo, Carles; Whiting, Andrew; Fernandez, Elena; (2015). Asymmetric metal free B-boration of a,B-unsaturated imines assisted by (S)-MeBoPhoz. Organic & Biomolecular Chemistry, 13(5), 1328-1332. DOI: 10.1039/c4ob02478h
Article's DOI: 10.1039/c4ob02478h
Entity: Universitat Rovira i Virgili
Journal publication year: 2015
Publication Type: Journal Publications
Repositori URV