Articles producció científicaQuímica Física i Inorgànica

Asymmetric metal free B-boration of a

  • Identification data

    Identifier:  imarina:3653867
    Handle: https://hdl.handle.net/20.500.11797/imarina3653867
    Authors:  La Cascia, Enrico; Sanz, Xavier; Bo, Carles; Whiting, Andrew; Fernandez, Elena
    Abstract:
    The adduct [MeO → Bpin-Bpin]- efficiently mediates the β-boration of α,β-unsaturated imines formed in situ. The use of chiral phosphines as additives, and in particular the chiral phosphine (S)-MeBoPhoz, enables the catalytic asymmetric reaction to proceed with higher enantioselectivity than the analogue copper(i) mediated reaction.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2015/ob/c4ob02478h
    APA: La Cascia, Enrico; Sanz, Xavier; Bo, Carles; Whiting, Andrew; Fernandez, Elena (2015). Asymmetric metal free B-boration of a,B-unsaturated imines assisted by (S)-MeBoPhoz. Organic & Biomolecular Chemistry, 13(5), 1328-1332. DOI: 10.1039/c4ob02478h
    Paper original source: Organic & Biomolecular Chemistry. 13 (5): 1328-1332
    Article's DOI: 10.1039/c4ob02478h
    Journal publication year: 2015
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: Bo Jané, Carles / Fernández Gutiérrez, Maria Elena / SANZ LÓPEZ, XAVIER
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: La Cascia, Enrico; Sanz, Xavier; Bo, Carles; Whiting, Andrew; Fernandez, Elena
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Physical and theoretical chemistry, Organic chemistry, Odontología, Medicina ii, Medicina i, Materiais, Interdisciplinar, General medicine, Farmacia, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Ciências agrárias i, Chemistry, organic, Biotecnología, Biodiversidade, Biochemistry
    Author's mail: carles.bo@urv.cat, mariaelena.fernandez@urv.cat

  • Keywords:

    Beta-boration
    Biochemistry
    Chemistry
    Organic
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Odontología
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    Farmacia
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Biotecnología
    Biodiversidade

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