Articles producció científica> Química Analítica i Química Orgànica

Broad scope gold(i)-catalysed polyenyne cyclisations for the formation of up to four carbon-carbon bonds

  • Identification data

    Identifier: imarina:3658067
    Authors:
    Rong, ZhoutingEchavarren, Antonio M.
    Abstract:
    The polycyclisation of polyenynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon-carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings. In addition to terminal alkynes, bromoalkynes can also be used as initiators of polyene cyclisations, giving rise to synthetically useful cyclic bromoalkenes.
  • Others:

    Author, as appears in the article.: Rong, Zhouting; Echavarren, Antonio M.;
    Department: Química Analítica i Química Orgànica
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Keywords: Cyclization Catalysis
    Abstract: The polycyclisation of polyenynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon-carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings. In addition to terminal alkynes, bromoalkynes can also be used as initiators of polyene cyclisations, giving rise to synthetically useful cyclic bromoalkenes.
    Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Odontología Medicina ii Medicina i Materiais Interdisciplinar General medicine Farmacia Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, organic Biotecnología Biodiversidade Biochemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: antoniomaria.echavarren@urv.cat
    Author identifier: 0000-0002-6418-7930
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2017/OB/C7OB00235A#!divAbstract
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Organic & Biomolecular Chemistry. 15 (10): 2163-2167
    APA: Rong, Zhouting; Echavarren, Antonio M.; (2017). Broad scope gold(i)-catalysed polyenyne cyclisations for the formation of up to four carbon-carbon bonds. Organic & Biomolecular Chemistry, 15(10), 2163-2167. DOI: 10.1039/c7ob00235a
    Article's DOI: 10.1039/c7ob00235a
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    Publication Type: Journal Publications
  • Keywords:

    Biochemistry,Chemistry, Organic,Organic Chemistry,Physical and Theoretical Chemistry
    Cyclization
    Catalysis
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Odontología
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    Farmacia
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, organic
    Biotecnología
    Biodiversidade
    Biochemistry
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