Articles producció científicaQuímica Física i Inorgànica

Pyrrolidine-Based P

  • Identification data

    Identifier:  imarina:4123867
    Handle: https://hdl.handle.net/20.500.11797/imarina4123867
    Authors:  Elias-Rodriguez, Pilar; Borras, Carlota; Carmona, Ana T; Faiges, Jorge; Robina, Inmaculada; Pamies, Oscar; Dieguez, Montserrat
    Abstract:
    © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The potential of P,O-iminosugar based ligands in the Ir-catalyzed asymmetric hydrogenation of minimally functionalized olefins is presented. These new ligands were prepared from easily available carbohydrates (D-mannose, D-ribose and D-arabinose). The stereochemical and polyfunctional diversity of carbohydrates allowed the modulation of the ligands, both from their electronic properties and the rigidity of their backbone. High enantioselectivities (ee’s up to 99 %) can be reached in the hydrogenation of selected tri- and disubstituted substrates.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201801485
    APA: Elias-Rodriguez, Pilar; Borras, Carlota; Carmona, Ana T; Faiges, Jorge; Robina, Inmaculada; Pamies, Oscar; Dieguez, Montserrat (2018). Pyrrolidine-Based P,O Ligands from Carbohydrates: Easily Accessible and Modular Ligands for the Ir-Catalyzed Asymmetric Hydrogenation of Minimally Functionalized Olefins. Chemcatchem, 10(23), 5414-5424. DOI: 10.1002/cctc.201801485
    Paper original source: Chemcatchem. 10 (23): 5414-5424
    Article's DOI: 10.1002/cctc.201801485
    Journal publication year: 2018
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2025-02-24
    First page: 5414
    URV's Author/s: BORRÀS NOGUERA, CARLOTA / Diéguez Fernández, Montserrat / Faiges Marcos, Jorge / Pamies Ollé, Oscar
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Last page: 5424
    ISSN: 1867-3880
    Author, as appears in the article.: Elias-Rodriguez, Pilar; Borras, Carlota; Carmona, Ana T; Faiges, Jorge; Robina, Inmaculada; Pamies, Oscar; Dieguez, Montserrat
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Journal volume: 10
    Thematic Areas: Química, Physical and theoretical chemistry, Organic chemistry, Medicina i, Materiais, Interdisciplinar, Inorganic chemistry, Farmacia, Engenharias iv, Engenharias iii, Engenharias ii, Engenharias i, Ciências biológicas ii, Ciências ambientais, Ciências agrárias i, Ciência de alimentos, Chemistry, physical, Catalysis, Biotecnología, Astronomia / física
    Author's mail: jorge.faiges@urv.cat, jorge.faiges@urv.cat, oscar.pamies@urv.cat, montserrat.dieguez@urv.cat

  • Keywords:

    Unfunctionalized
    Scope
    Phosphite
    P
    o ligands
    Olefins
    Library
    Iridium
    Complex
    Asymmetric hydrogenation
    Alpha
    Catalysis
    Chemistry
    Physical
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Medicina i
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Biotecnología
    Astronomia / física

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