e-ISSN: 1867-3899
Project code: CTQ2016-75016-R
Keywords: Ligand effects Homogeneous catalysis High molecular weight polypropylenecarbonate Cobalt salen catalysis Co2 transformations Co transformations 2
Research group: Organometàl.lics i Catàlisi Homogènia Síntesis Orgànica Estereoselectiva
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/publishedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemcatchem. 9 (20): 3974-3981
APA: Viciano M; Muñoz B; Godard C; Castillón S; Reyes M; García-Ruiz M; Claver C (2017). Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates. Chemcatchem, 9(20), 3974-3981. DOI: 10.1002/cctc.201701250
Acronym: ECO2VALCAT
Publication Type: Journal Publications
Author, as appears in the article.: Viciano M; Muñoz B; Godard C; Castillón S; Reyes M; García-Ruiz M; Claver C
Department: Química Física i Inorgànica Química Analítica i Química Orgànica
URV's Author/s: Castillón Miranda, Sergio / Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
Abstract: High molecular weight polypropylene carbonates were prepared by CO2/propylene oxide copolymerization catalyzed by salcy-naphthalene cobalt complexes. The introduction of methyl groups in the ortho position of naphthalene-based salcy ligands and the catalyst loading in the presence of hexane as a co-solvent were crucial to enhance the catalytic performance for the production of polycarbonates of high molecular weight.
Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1867-3880
Author's mail: cyril.godard@urv.cat sergio.castillon@urv.cat carmen.claver@urv.cat
Author identifier: 0000-0001-5762-4904 0000-0002-0690-7549 0000-0002-2518-7401
Project code 2: TQC14029S; TQC16006S
Founding program 2: altres; Repsol and CTQC
Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
Founding program 4: altres; EEA Financial Mechanism; EEA Grants
Founding program 3: altres; CDTI; NEOSPOL; IDI2014- 0116
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
Repositori URV