Articles producció científicaQuímica Física i Inorgànica

Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates

  • Identification data

    Identifier:  imarina:5131899
    Handle: https://hdl.handle.net/20.500.11797/imarina5131899
    Authors:  Viciano, M; Muñoz, BK; Godard, C; Castillón, S; Reyes, ML; García-Ruiz, M; Claver, C
    Abstract:
    High molecular weight polypropylene carbonates were prepared by CO2/propylene oxide copolymerization catalyzed by salcy-naphthalene cobalt complexes. The introduction of methyl groups in the ortho position of naphthalene-based salcy ligands and the catalyst loading in the presence of hexane as a co-solvent were crucial to enhance the catalytic performance for the production of polycarbonates of high molecular weight.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201701250
    Paper original source: ChemCatChem. 9 (20): 3974-3981
    Entity: Universitat Rovira i Virgili
    Record's date: 2026-05-09
    URV's Author/s: Castillón Miranda, Sergio / Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
    Project code 2: TQC14029S; TQC16006S
    Department: Química Física i Inorgànica, Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Founding program 3: altres; CDTI; NEOSPOL; IDI2014- 0116
    Founding program 4: altres; EEA Financial Mechanism; EEA Grants
    ISSN: 1867-3880
    Founding program 2: altres; Repsol and CTQC
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    e-ISSN: 1867-3899
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, Inorganic chemistry, Chemistry, physical, Catalysis, Biotecnología, Astronomia / física
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    APA: Viciano, M; Muñoz, BK; Godard, C; Castillón, S; Reyes, ML; García-Ruiz, M; Claver, C (2017). Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates. ChemCatChem, 9(20), 3974-3981. DOI: 10.1002/cctc.201701250
    Article's DOI: 10.1002/cctc.201701250
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Journal publication year: 2017-10-23
    Paper version: info:eu-repo/semantics/publishedVersion
    Acronym: ECO2VALCAT
    Author, as appears in the article.: Viciano, M; Muñoz, BK; Godard, C; Castillón, S; Reyes, ML; García-Ruiz, M; Claver, C
    Project code: CTQ2016-75016-R
    Research group: Organometàl.lics i Catàlisi Homogènia, Síntesis Orgànica Estereoselectiva
    Author's mail: sergio.castillon@urv.cat, sergio.castillon@urv.cat, carmen.claver@urv.cat, carmen.claver@urv.cat, cyril.godard@urv.cat, cyril.godard@urv.cat

  • Keywords:

    Ligand effects
    Homogeneous catalysis
    High molecular weight polypropylenecarbonate
    Cobalt salen catalysis
    Co2 transformations
    Co transformations 2
    Catalysis
    Chemistry
    Physical
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Biotecnología
    Astronomia / física

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