Articles producció científica> Química Física i Inorgànica

Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates

  • Identification data

    Identifier: imarina:5131899
    Authors:
    Viciano MMuñoz BGodard CCastillón SReyes MGarcía-Ruiz MClaver C
    Abstract:
    High molecular weight polypropylene carbonates were prepared by CO2/propylene oxide copolymerization catalyzed by salcy-naphthalene cobalt complexes. The introduction of methyl groups in the ortho position of naphthalene-based salcy ligands and the catalyst loading in the presence of hexane as a co-solvent were crucial to enhance the catalytic performance for the production of polycarbonates of high molecular weight.
  • Others:

    e-ISSN: 1867-3899
    Project code: CTQ2016-75016-R
    Keywords: Ligand effects Homogeneous catalysis High molecular weight polypropylenecarbonate Cobalt salen catalysis Co2 transformations Co transformations 2
    Research group: Organometàl.lics i Catàlisi Homogènia Síntesis Orgànica Estereoselectiva
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Chemcatchem. 9 (20): 3974-3981
    APA: Viciano M; Muñoz B; Godard C; Castillón S; Reyes M; García-Ruiz M; Claver C (2017). Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates. Chemcatchem, 9(20), 3974-3981. DOI: 10.1002/cctc.201701250
    Acronym: ECO2VALCAT
    Publication Type: Journal Publications
    Author, as appears in the article.: Viciano M; Muñoz B; Godard C; Castillón S; Reyes M; García-Ruiz M; Claver C
    Department: Química Física i Inorgànica Química Analítica i Química Orgànica
    URV's Author/s: Castillón Miranda, Sergio / Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
    Abstract: High molecular weight polypropylene carbonates were prepared by CO2/propylene oxide copolymerization catalyzed by salcy-naphthalene cobalt complexes. The introduction of methyl groups in the ortho position of naphthalene-based salcy ligands and the catalyst loading in the presence of hexane as a co-solvent were crucial to enhance the catalytic performance for the production of polycarbonates of high molecular weight.
    Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1867-3880
    Author's mail: cyril.godard@urv.cat sergio.castillon@urv.cat carmen.claver@urv.cat
    Author identifier: 0000-0001-5762-4904 0000-0002-0690-7549 0000-0002-2518-7401
    Project code 2: TQC14029S; TQC16006S
    Founding program 2: altres; Repsol and CTQC
    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201701250
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Founding program 4: altres; EEA Financial Mechanism; EEA Grants
    Founding program 3: altres; CDTI; NEOSPOL; IDI2014- 0116
    Article's DOI: 10.1002/cctc.201701250
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
  • Keywords:

    Catalysis,Chemistry, Physical,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Ligand effects
    Homogeneous catalysis
    High molecular weight polypropylenecarbonate
    Cobalt salen catalysis
    Co2 transformations
    Co transformations 2
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Catalysis
    Biotecnología
    Astronomia / física
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