Articles producció científicaQuímica Física i Inorgànica

Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates

  • Identification data

    Identifier:  imarina:5131899
    Handle: https://hdl.handle.net/20.500.11797/imarina5131899
    Authors:  Viciano, Monica; Munoz, Bianca K; Godard, Cyril; Castillon, Sergio; Reyes, Manuel L; Garcia-Ruiz, Monica; Claver, Carmen
    Abstract:
    High molecular weight polypropylene carbonates were prepared by CO2/propylene oxide copolymerization catalyzed by salcy-naphthalene cobalt complexes. The introduction of methyl groups in the ortho position of naphthalene-based salcy ligands and the catalyst loading in the presence of hexane as a co-solvent were crucial to enhance the catalytic performance for the production of polycarbonates of high molecular weight.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201701250
    Paper original source: Chemcatchem. 9 (20): 3974-3981
    Entity: Universitat Rovira i Virgili
    Record's date: 2025-01-28
    URV's Author/s: Castillón Miranda, Sergio / Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
    Project code 2: TQC14029S; TQC16006S
    Department: Química Física i Inorgànica, Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Founding program 3: altres; CDTI; NEOSPOL; IDI2014- 0116
    Founding program 4: altres; EEA Financial Mechanism; EEA Grants
    ISSN: 1867-3880
    Founding program 2: altres; Repsol and CTQC
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    e-ISSN: 1867-3899
    Thematic Areas: Química, Physical and theoretical chemistry, Organic chemistry, Medicina i, Materiais, Interdisciplinar, Inorganic chemistry, Farmacia, Engenharias iv, Engenharias iii, Engenharias ii, Engenharias i, Ciências biológicas ii, Ciências ambientais, Ciências agrárias i, Ciência de alimentos, Chemistry, physical, Catalysis, Biotecnología, Astronomia / física
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    APA: Viciano, Monica; Munoz, Bianca K; Godard, Cyril; Castillon, Sergio; Reyes, Manuel L; Garcia-Ruiz, Monica; Claver, Carmen (2017). Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates. Chemcatchem, 9(20), 3974-3981. DOI: 10.1002/cctc.201701250
    Article's DOI: 10.1002/cctc.201701250
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Journal publication year: 2017
    Paper version: info:eu-repo/semantics/publishedVersion
    Acronym: ECO2VALCAT
    Author, as appears in the article.: Viciano, Monica; Munoz, Bianca K; Godard, Cyril; Castillon, Sergio; Reyes, Manuel L; Garcia-Ruiz, Monica; Claver, Carmen
    Project code: CTQ2016-75016-R
    Research group: Organometàl.lics i Catàlisi Homogènia, Síntesis Orgànica Estereoselectiva
    Author's mail: cyril.godard@urv.cat, sergio.castillon@urv.cat, carmen.claver@urv.cat

  • Keywords:

    Ligand effects
    Homogeneous catalysis
    High molecular weight polypropylenecarbonate
    Cobalt salen catalysis
    Co2 transformations
    Co transformations 2
    Catalysis
    Chemistry
    Physical
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Medicina i
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Biotecnología
    Astronomia / física

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