Author, as appears in the article.: Granados-Reyes J, Salagre P, Cesteros Y
Department: Química Física i Inorgànica
URV's Author/s: Cesteros Fernández, Yolanda / Salagre Carnero, María Pilar
Keywords: Transesterification Organic-synthesis Microwaves Layered double hydroxides Hydrotalcite catalyst Hydrocalumite-type materials Glycerol carbonate Glycerol Dimethyl carbonate Derivatives Biodiesel Base catalysts Assisted synthesis
Abstract: Several hydrocalumite-type materials and some of their calcined forms have been tested for the catalytic transesterification of glycerol towards glycerol carbonate under microwaves, and by conventional heating for comparison. Microwaves slightly increased conversion but greatly increased selectivity to glycerol carbonate for all catalysts while the selectivity to glycidol was similar. Glycerol conversion values were 63-95% in microwaves and 61-91% by conventional heating, while selectivity to glycerol carbonate values were 53-92% in microwaves and 30-80% by conventional heating. Interestingly, microwaves favored transesterification since the sum of the selectivity values to glycerol carbonate and glycidol was higher than when using conventional heating.
Thematic Areas: Water science and technology Soil science Química Mineralogy Medicina veterinaria Medicina ii Materials science, multidisciplinary Materiais Interdisciplinar Geology Geografía Geociências Geochemistry and petrology Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Biotecnología Astronomia / física Arquitetura, urbanismo e design Arquitetura e urbanismo Antropologia / arqueologia
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 01691317
Author's mail: yolanda.cesteros@urv.cat
Author identifier: 0000-0002-5439-9358
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0169131718300310
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Applied Clay Science. 156 110-115
APA: Granados-Reyes J, Salagre P, Cesteros Y (2018). Boosted selectivity towards glycerol carbonate using microwaves vs conventional heating for the catalytic transesterification of glycerol. Applied Clay Science, 156(), 110-115. DOI: 10.1016/j.clay.2018.01.025
Article's DOI: 10.1016/j.clay.2018.01.025
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
Publication Type: Journal Publications
Repositori URV