Author, as appears in the article.: Dias, Lucas D.; Carrilho, Rui M. B.; Henriques, Cesar A.; Calvete, Mario J. F.; Masdeu-Bulto, Anna M.; Claver, Carmen; Rossi, Liane M.; Pereira, Mariette M.;
Department: Química Física i Inorgànica
URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria
Project code: CTQ2016-75016-R
Keywords: Sequential processes Metalloporphyrins Magnetic nanoparticles Hybrid magnetic nanoparticles Epoxidation Co cycloaddition 2
Abstract: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates.
Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: annamaria.masdeu@urv.cat carmen.claver@urv.cat
Author identifier: 0000-0001-7938-3902 0000-0002-2518-7401
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/acceptedVersion
Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemcatchem. 10 (13): 2792-2803
APA: Dias, Lucas D.; Carrilho, Rui M. B.; Henriques, Cesar A.; Calvete, Mario J. F.; Masdeu-Bulto, Anna M.; Claver, Carmen; Rossi, Liane M.; Pereira, Marie (2018). Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates. Chemcatchem, 10(13), 2792-2803. DOI: 10.1002/cctc.201800397
Acronym: ECO2VALCAT
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
Publication Type: Journal Publications
Repositori URV