Articles producció científicaQuímica Física i Inorgànica

Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates

  • Identification data

    Identifier:  imarina:5132037
    Handle: https://hdl.handle.net/20.500.11797/imarina5132037
    Authors:  Dias, LD; Carrilho, RMB; Henriques, CA; Calvete, MJF; Masdeu-Bultó, AM; Claver, C; Rossi, LM; Pereira, MM
    Abstract:
    © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201800397
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    APA: Dias, LD; Carrilho, RMB; Henriques, CA; Calvete, MJF; Masdeu-Bultó, AM; Claver, C; Rossi, LM; Pereira, MM (2018). Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates. Chemcatchem, 10(13), 2792-2803. DOI: 10.1002/cctc.201800397
    Paper original source: Chemcatchem. 10 (13): 2792-2803
    Article's DOI: 10.1002/cctc.201800397
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Journal publication year: 2018-07-09
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2026-05-09
    URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Acronym: ECO2VALCAT
    Publication Type: Journal Publications
    Author, as appears in the article.: Dias, LD; Carrilho, RMB; Henriques, CA; Calvete, MJF; Masdeu-Bultó, AM; Claver, C; Rossi, LM; Pereira, MM
    Project code: CTQ2016-75016-R
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, Inorganic chemistry, Chemistry, physical, Catalysis, Biotecnología, Astronomia / física
    Author's mail: carmen.claver@urv.cat, carmen.claver@urv.cat, annamaria.masdeu@urv.cat, annamaria.masdeu@urv.cat

  • Keywords:

    Sequential processes
    Metalloporphyrins
    Magnetic nanoparticles
    Hybrid magnetic nanoparticles
    Epoxidation
    Co cycloaddition 2
    Catalysis
    Chemistry
    Physical
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Biotecnología
    Astronomia / física

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