Articles producció científicaQuímica Física i Inorgànica

Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates

  • Identification data

    Identifier:  imarina:5132037
    Handle: https://hdl.handle.net/20.500.11797/imarina5132037
    Authors:  Dias, Lucas D; Carrilho, Rui M B; Henriques, Cesar A; Calvete, Mario J F; Masdeu-Bulto, Anna M; Claver, Carmen; Rossi, Liane M; Pereira, Mariette M
    Abstract:
    © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201800397
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    APA: Dias, Lucas D; Carrilho, Rui M B; Henriques, Cesar A; Calvete, Mario J F; Masdeu-Bulto, Anna M; Claver, Carmen; Rossi, Liane M; Pereira, Mariette M (2018). Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates. Chemcatchem, 10(13), 2792-2803. DOI: 10.1002/cctc.201800397
    Paper original source: Chemcatchem. 10 (13): 2792-2803
    Article's DOI: 10.1002/cctc.201800397
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Journal publication year: 2018
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2025-01-08
    URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Acronym: ECO2VALCAT
    Publication Type: Journal Publications
    Author, as appears in the article.: Dias, Lucas D; Carrilho, Rui M B; Henriques, Cesar A; Calvete, Mario J F; Masdeu-Bulto, Anna M; Claver, Carmen; Rossi, Liane M; Pereira, Mariette M
    Project code: CTQ2016-75016-R
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Physical and theoretical chemistry, Organic chemistry, Medicina i, Materiais, Interdisciplinar, Inorganic chemistry, Farmacia, Engenharias iv, Engenharias iii, Engenharias ii, Engenharias i, Ciências biológicas ii, Ciências ambientais, Ciências agrárias i, Ciência de alimentos, Chemistry, physical, Catalysis, Biotecnología, Astronomia / física
    Author's mail: annamaria.masdeu@urv.cat, carmen.claver@urv.cat

  • Keywords:

    Sequential processes
    Metalloporphyrins
    Magnetic nanoparticles
    Hybrid magnetic nanoparticles
    Epoxidation
    Co cycloaddition 2
    Catalysis
    Chemistry
    Physical
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Medicina i
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Biotecnología
    Astronomia / física

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