Author, as appears in the article.: Dias, Lucas D.; Carrilho, Rui M. B.; Henriques, Cesar A.; Calvete, Mario J. F.; Masdeu-Bulto, Anna M.; Claver, Carmen; Rossi, Liane M.; Pereira, Mariette M.;

Department: Química Física i Inorgànica

URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria

Project code: CTQ2016-75016-R

Keywords: Sequential processes Metalloporphyrins Magnetic nanoparticles Hybrid magnetic nanoparticles Epoxidation Co cycloaddition 2

Abstract: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates.

Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

Author's mail: carmen.claver@urv.cat annamaria.masdeu@urv.cat

Author identifier: 0000-0002-2518-7401 0000-0001-7938-3902

Record's date: 2023-09-02

Papper version: info:eu-repo/semantics/acceptedVersion

Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201800397

Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Chemcatchem. 10 (13): 2792-2803

APA: Dias, Lucas D.; Carrilho, Rui M. B.; Henriques, Cesar A.; Calvete, Mario J. F.; Masdeu-Bulto, Anna M.; Claver, Carmen; Rossi, Liane M.; Pereira, Marie (2018). Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates. Chemcatchem, 10(13), 2792-2803. DOI: 10.1002/cctc.201800397

Acronym: ECO2VALCAT

Article's DOI: 10.1002/cctc.201800397

Entity: Universitat Rovira i Virgili

Journal publication year: 2018

Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS

Publication Type: Journal Publications