Articles producció científica> Química Física i Inorgànica

Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates

  • Identification data

    Identifier: imarina:5132037
    Authors:
    Dias, Lucas D.Carrilho, Rui M. B.Henriques, Cesar A.Calvete, Mario J. F.Masdeu-Bulto, Anna M.Claver, CarmenRossi, Liane M.Pereira, Mariette M.
    Abstract:
    © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates.
  • Others:

    Author, as appears in the article.: Dias, Lucas D.; Carrilho, Rui M. B.; Henriques, Cesar A.; Calvete, Mario J. F.; Masdeu-Bulto, Anna M.; Claver, Carmen; Rossi, Liane M.; Pereira, Mariette M.;
    Department: Química Física i Inorgànica
    URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria
    Project code: CTQ2016-75016-R
    Keywords: Sequential processes Metalloporphyrins Magnetic nanoparticles Hybrid magnetic nanoparticles Epoxidation Co cycloaddition 2
    Abstract: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates.
    Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: annamaria.masdeu@urv.cat carmen.claver@urv.cat
    Author identifier: 0000-0001-7938-3902 0000-0002-2518-7401
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201800397
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Chemcatchem. 10 (13): 2792-2803
    APA: Dias, Lucas D.; Carrilho, Rui M. B.; Henriques, Cesar A.; Calvete, Mario J. F.; Masdeu-Bulto, Anna M.; Claver, Carmen; Rossi, Liane M.; Pereira, Marie (2018). Hybrid-Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates. Chemcatchem, 10(13), 2792-2803. DOI: 10.1002/cctc.201800397
    Acronym: ECO2VALCAT
    Article's DOI: 10.1002/cctc.201800397
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2018
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    Publication Type: Journal Publications
  • Keywords:

    Catalysis,Chemistry, Physical,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Sequential processes
    Metalloporphyrins
    Magnetic nanoparticles
    Hybrid magnetic nanoparticles
    Epoxidation
    Co cycloaddition 2
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Catalysis
    Biotecnología
    Astronomia / física
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