Articles producció científica> Química Física i Inorgànica

Double functionalization of a fullerene in drastic arc-discharge conditions: synthesis and formation mechanism of C-2v(2)-C78Cl6(C5Cl6)

  • Identification data

    Identifier: imarina:5132038
    Authors:
    Gao C, Abella L, Tian H, Zhang X, Zhong Y, Tan Y, Wu X, Rodríguez-Fortea A, Poblet J, Xie S, Huang R, Zheng L
    Abstract:
    Arc-discharge of graphite is the most prevalent technique for synthesis of novel fullerenes, but the extreme conditions of the carbon arc prevent any currently available instrument from detecting the reaction species inside. To detour the difficulties for probing the derivatization mechanism in the drastic arc-discharge conditions, C78Cl6(C5Cl6) with prototypical C2v(2)-C78 cage has been isolated and characterized in the products of the chlorine-involving carbon arc. The structure of C2v(2)-C78Cl6(C5Cl6), featuring with fullerene C2v(2)-C78 doubly functionalized by chlorine atoms and perchlorinated cyclopentadiene, has been identified by X-ray crystallography. Confirmed by standard Density Functional Theory (DFT) calculations and Car-Parrinello simulations as well as mass spectrometry, the fullerene core has been revealed to form firstly followed then by reaction with chlorine atoms and afterwards with perchlorinated cyclopentadiene, with implication about stepwise reaction temperatures and sequences for the formation of fullerenes and their derivatives in the otherwise inaccessible extreme conditions of the carbon arc.
  • Others:

    Author, as appears in the article.: Gao C, Abella L, Tian H, Zhang X, Zhong Y, Tan Y, Wu X, Rodríguez-Fortea A, Poblet J, Xie S, Huang R, Zheng L
    Department: Química Física i Inorgànica
    URV's Author/s: Poblet Rius, Josep Maria / Rodríguez Fortea, Antonio
    Keywords: Fullerenes Electric arcs
    Abstract: Arc-discharge of graphite is the most prevalent technique for synthesis of novel fullerenes, but the extreme conditions of the carbon arc prevent any currently available instrument from detecting the reaction species inside. To detour the difficulties for probing the derivatization mechanism in the drastic arc-discharge conditions, C78Cl6(C5Cl6) with prototypical C2v(2)-C78 cage has been isolated and characterized in the products of the chlorine-involving carbon arc. The structure of C2v(2)-C78Cl6(C5Cl6), featuring with fullerene C2v(2)-C78 doubly functionalized by chlorine atoms and perchlorinated cyclopentadiene, has been identified by X-ray crystallography. Confirmed by standard Density Functional Theory (DFT) calculations and Car-Parrinello simulations as well as mass spectrometry, the fullerene core has been revealed to form firstly followed then by reaction with chlorine atoms and afterwards with perchlorinated cyclopentadiene, with implication about stepwise reaction temperatures and sequences for the formation of fullerenes and their derivatives in the otherwise inaccessible extreme conditions of the carbon arc.
    Thematic Areas: Química Medicina iii Medicina i Materials science, multidisciplinary Materials science (miscellaneous) Materials science (all) Materials science Materiais Interdisciplinar General materials science General chemistry Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências ambientais Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 00086223
    Author's mail: josepmaria.poblet@urv.cat antonio.rodriguezf@urv.cat
    Author identifier: 0000-0002-4533-0623 0000-0001-5884-5629
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0008622317312198
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Carbon. 129 286-292
    APA: Gao C, Abella L, Tian H, Zhang X, Zhong Y, Tan Y, Wu X, Rodríguez-Fortea A, Poblet J, Xie S, Huang R, Zheng L (2018). Double functionalization of a fullerene in drastic arc-discharge conditions: synthesis and formation mechanism of C-2v(2)-C78Cl6(C5Cl6). Carbon, 129(), 286-292. DOI: 10.1016/j.carbon.2017.11.097
    Article's DOI: 10.1016/j.carbon.2017.11.097
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2018
    Publication Type: Journal Publications
  • Keywords:

    Chemistry (Miscellaneous),Chemistry, Physical,Materials Science,Materials Science (Miscellaneous),Materials Science, Multidisciplinary
    Fullerenes
    Electric arcs
    Química
    Medicina iii
    Medicina i
    Materials science, multidisciplinary
    Materials science (miscellaneous)
    Materials science (all)
    Materials science
    Materiais
    Interdisciplinar
    General materials science
    General chemistry
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Chemistry, physical
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Astronomia / física
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