Author, as appears in the article.: Amadio E., González-Fabra J., Carraro D., Denis W., Gjoka B., Zonta C., Bartik K., Cavani F., Solmi S., Bo C., Licini G.
Department: Química Física i Inorgànica
URV's Author/s: Bo Jané, Carles
Keywords: Vanadium Vanadi Oxygen Oxidació aeróbica Homogeneous catalysis C?c activation C-c activation Aerobic oxidation
Abstract: The aerobic oxidative C−C bond cleavage of vicinal diols catalyzed by vanadium amino triphenolates is described. Our results show that C−C bond cleavage can be performed in different solvents, under an air or oxygen atmosphere, with a large variety of glycols (cyclic or linear, with aromatic or aliphatic substituents) affording the corresponding carbonyl derivatives with high chemoselectivity. Reactions can be performed with as little as 10 ppm of catalyst reaching TON up to 81,000 and TOFs of up to 4150 h−1. A reaction mechanism, rationalized by density functional theory calculations, is also proposed.
Thematic Areas: Química Organic chemistry Materiais Engenharias iv Engenharias ii Ciências biológicas ii Ciência de alimentos Chemistry, organic Chemistry, applied Catalysis Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 16154150
Author's mail: carles.bo@urv.cat
Author identifier: 0000-0001-9581-2922
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Advanced Synthesis & Catalysis. 360 (17): 3286-3296
APA: Amadio E., González-Fabra J., Carraro D., Denis W., Gjoka B., Zonta C., Bartik K., Cavani F., Solmi S., Bo C., Licini G. (2018). Efficient Vanadium-Catalyzed Aerobic C-C Bond Oxidative Cleavage of Vicinal Diols. Advanced Synthesis & Catalysis, 360(17), 3286-3296. DOI: 10.1002/adsc.201800050
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
Publication Type: Journal Publications
Repositori URV