Author, as appears in the article.: Guzman, Dailyn; Ramis, Xavier; Fernandez-Francos, Xavier; Serra, Angels
Department: Enginyeria Mecànica Química Analítica i Química Orgànica
e-ISSN: 2073-4360
URV's Author/s: Fernández Francos, Xavier / Serra Albet, Maria Angels
Keywords: Triglycidyl isocyanurate Thiol Thermosets Latency Epoxy resin Click reaction
Abstract: Tri and tetrafunctional thiol were used as curing agent for diglycidyl ether of bisphenol A (DGEBA) catalyzed by a commercially available amine precursor, LC-80. Triglycidyl isocianurate (TGIC) was added in different proportions to the mixture to increase rigidity and glass transition temperature (Tg). The cooperative effect of increasing functionality of thiol and the presence of TGIC in the formulation leads to an increased Tg without affecting thermal stability. The kinetics of the curing of mixtures was studied by calorimetry under isothermal and non-isothermal conditions. The latent characteristics of the formulations containing amine precursors were investigated by rheometry and calorimetry. The increase in the functionality of the thiol produces a slight decrease in the storage lifetime of the mixture. The materials obtained with tetrathiol as curing agent showed the highest values of Young's modulus and Tg.
Thematic Areas: Polymers and plastics Polymer science Odontología General chemistry Farmacia Engenharias ii Ciências biológicas ii Chemistry (miscellaneous) Chemistry (all) Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 20734360
Author's mail: angels.serra@urv.cat xavier.fernandez@urv.cat
Author identifier: 0000-0003-1387-0358 0000-0002-3492-2922
Last page: 694
Record's date: 2024-09-07
Journal volume: 7
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://www.mdpi.com/2073-4360/7/4/680
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Polymers. 7 (4): 680-694
APA: Guzman, Dailyn; Ramis, Xavier; Fernandez-Francos, Xavier; Serra, Angels (2015). Enhancement in the Glass Transition Temperature in Latent Thiol-Epoxy Click Cured Thermosets. Polymers, 7(4), 680-694. DOI: 10.3390/polym7040680
Article's DOI: 10.3390/polym7040680
Entity: Universitat Rovira i Virgili
Journal publication year: 2015
First page: 680
Publication Type: Journal Publications
Repositori URV