Author, as appears in the article.: Moncea, Oana; Casanova-Chafer, Juan; Poinsot, Didier; Ochmann, Lukas; Mboyi, Cleve D; Nasrallah, Houssein O; Llobet, Eduard; Makni, Imen; El Atrous, Molka; Brandes, Stephane; Rousselin, Yoann; Domenichini, Bruno; Nuns, Nicolas; Fokin, Andrey A; Schreiner, Peter R; Hierso, Jean-Cyrille
Department: Enginyeria Electrònica, Elèctrica i Automàtica
URV's Author/s: Casanova Chafer, Juan / Llobet Valero, Eduard
Keywords: Phosphine Palladium Nanodiamonds Hybrid materials Gas sensing palladium nanodiamonds hybrid materials gas sensing
Abstract: Diamondoids, sp3 -hybridized nanometer-sized diamond-like hydrocarbons (nanodiamonds), difunctionalized with hydroxy and primary phosphine oxide groups, enable the assembly of the first sp3 -C-based chemical sensors by vapor deposition. Both pristine nanodiamonds and palladium nanolayered composites can be used to detect toxic NO2 and NH3 gases. This carbon-based gas sensor technology allows reversible NO2 detection down to 50?ppb and NH3 detection at 25-100?ppm concentration with fast response and recovery processes at 100?°C. Reversible gas adsorption and detection is compatible with 50?% humidity conditions. Semiconducting p-type sensing properties are achieved from devices based on primary phosphine-diamantanol, in which high specific area (ca. 140?m2 ?g-1 ) and channel nanoporosity derive from H-bonding.© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thematic Areas: Química Medicina ii Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14337851
Author's mail: juan.casanova@urv.cat eduard.llobet@urv.cat
Author identifier: 0000-0001-6164-4342
Record's date: 2024-10-12
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Angewandte Chemie (International Ed. Print). 58 (29): 9933-9938
APA: Moncea, Oana; Casanova-Chafer, Juan; Poinsot, Didier; Ochmann, Lukas; Mboyi, Cleve D; Nasrallah, Houssein O; Llobet, Eduard; Makni, Imen; El Atrous, M (2019). Diamondoid Nanostructures as sp3-Carbon-Based Gas Sensors. Angewandte Chemie (International Ed. Print), 58(29), 9933-9938. DOI: 10.1002/anie.201903089
Entity: Universitat Rovira i Virgili
Journal publication year: 2019
Publication Type: Journal Publications
Repositori URV