Articles producció científicaQuímica Analítica i Química Orgànica

Gold(I)-Catalyzed Intramolecular C(sp3 )-H Insertion by Decarbenation of Cycloheptatrienes

  • Identification data

    Identifier:  imarina:5873662
    Handle: https://hdl.handle.net/20.500.11797/imarina5873662
    Authors:  Yin, Xiang; Zuccarello, Giuseppe; Garcia-Morales, Cristina; Echavarren, Antonio M
    Abstract:
    A novel synthesis of indanes and dihydronaphtalenes based on the intramolecular insertion into C(sp3 )-H bonds of gold(I) carbenes generated by retro-Buchner reaction (decarbenation) has been developed. Deuterium-labeling and kinetic isotope effect experiments, DFT calculations, and generation of the proposed carbene intermediate from a well-characterized gold(I) carbenoid support the involvement of a three-center concerted mechanism for the C(sp3 )-H functionalization process.© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201900919
    APA: Yin, Xiang; Zuccarello, Giuseppe; Garcia-Morales, Cristina; Echavarren, Antonio M (2019). Gold(I)-Catalyzed Intramolecular C(sp3 )-H Insertion by Decarbenation of Cycloheptatrienes. Chemistry-A European Journal, 25(40), 9485-9490. DOI: 10.1002/chem.201900919
    Paper original source: Chemistry-A European Journal. 25 (40): 9485-9490
    Article's DOI: 10.1002/chem.201900919
    Journal publication year: 2019
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-19
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    ISSN: 15213765
    Author, as appears in the article.: Yin, Xiang; Zuccarello, Giuseppe; Garcia-Morales, Cristina; Echavarren, Antonio M
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Organic chemistry, Medicina i, Materiais, Interdisciplinar, General medicine, General chemistry, Farmacia, Engenharias iii, Engenharias ii, Ciências biológicas iii, Ciências biológicas ii, Ciências biológicas i, Ciências agrárias i, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Biotecnología, Biodiversidade, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat

  • Keywords:

    Retro-buchner reaction
    Natural-products
    Indanes
    Gold(i) carbenes
    Gold catalysis
    Generation
    Decarbenation
    C−h insertion
    Complexes
    Carbenes
    C?h insertion
    C-h insertion
    Bond functionalization
    Alkanes
    Activation
    Access
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Organic Chemistry
    Química
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry (all)
    Biotecnología
    Biodiversidade
    Astronomia / física

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