Author, as appears in the article.: Yin X, Zuccarello G, García-Morales C, Echavarren AM
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO
Keywords: Retro-buchner reaction Natural-products Indanes Gold(i) carbenes Gold catalysis Generation Decarbenation C−h insertion Complexes Carbenes C?h insertion C-h insertion Bond functionalization Alkanes Activation Access
Abstract: A novel synthesis of indanes and dihydronaphtalenes based on the intramolecular insertion into C(sp3 )-H bonds of gold(I) carbenes generated by retro-Buchner reaction (decarbenation) has been developed. Deuterium-labeling and kinetic isotope effect experiments, DFT calculations, and generation of the proposed carbene intermediate from a well-characterized gold(I) carbenoid support the involvement of a three-center concerted mechanism for the C(sp3 )-H functionalization process.© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thematic Areas: Química Organic chemistry Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biotecnología Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 15213765
Author's mail: antoniomaria.echavarren@urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2023-07-31
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201900919
Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemistry-A European Journal. 25 (40): 9485-9490
APA: Yin X, Zuccarello G, García-Morales C, Echavarren AM (2019). Gold(I)-Catalyzed Intramolecular C(sp3 )-H Insertion by Decarbenation of Cycloheptatrienes. Chemistry-A European Journal, 25(40), 9485-9490. DOI: 10.1002/chem.201900919
Article's DOI: 10.1002/chem.201900919
Entity: Universitat Rovira i Virgili
Journal publication year: 2019
Publication Type: Journal Publications
Repositori URV