Author, as appears in the article.: García-Morales C, Pei XL, Sarria Toro JM, Echavarren AM
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO
Keywords: Structure elucidation Retro-buchner reaction Reactivity Mechanism Gold Generation Density-functional calculations Decomposition Complexes Cis Catalysis Carbenoids Carbenes Access
Abstract: Mesityl gold(I) carbenes lacking heteroatom stabilization or shielding ancillary ligands have been generated and spectroscopically characterized from chloro(mesityl)methylgold(I) carbenoids bearing JohnPhos-type ligands by chloride abstraction with GaCl3 . The aryl carbenes react with PPh3 and alkenes to give stable phosphonium ylides and cyclopropanes, respectively. Oxidation with pyridine N-oxide and intermolecular C-H insertion to cyclohexane have also been observed. In the absence of nucleophiles, a bimolecular reaction, similar to that observed for other metal carbenes, leads to a symmetrical alkene.© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thematic Areas: Química Medicina ii Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14337851
Author's mail: antoniomaria.echavarren@urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2022-07-23
Papper version: info:eu-repo/semantics/publishedVersion
Papper original source: Angewandte Chemie (International Ed. Print). 58 (12): 3957-3961
APA: García-Morales C, Pei XL, Sarria Toro JM, Echavarren AM (2019). Direct Observation of Aryl Gold(I) Carbenes that Undergo Cyclopropanation, C-H Insertion, and Dimerization Reactions. Angewandte Chemie (International Ed. Print), 58(12), 3957-3961. DOI: 10.1002/anie.201814577
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2019
Publication Type: Journal Publications
Repositori URV