Articles producció científicaQuímica Física i Inorgànica

Efficient synthesis of chiral γ-aminobutyric esters: Via direct rhodium-catalysed enantioselective hydroaminomethylation of acrylates

  • Identification data

    Identifier:  imarina:6112283
    Handle: https://hdl.handle.net/20.500.11797/imarina6112283
    Authors:  Cunillera, Anton; Diaz de los Bernardos, Miriam; Urrutigoity, Martine; Claver, Carmen; Ruiz, Aurora; Godard, Cyril
    Abstract:
    This journal is © The Royal Society of Chemistry. The successful rhodium catalysed asymmetric intermolecular hydroaminomethylation (HAM) of alkenes using a single catalyst bearing the (R,R)-QuinoxP∗ ligand is reported. The HAM of α-alkyl acrylates is revealed to be an efficient tool for the regio- and enantioselective synthesis of γ-amino esters with ees up to 86%. HPNMR experiments provided insights into the reaction mechanism.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2020/cy/c9cy01797f#!divAbstract
    Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    APA: Cunillera, Anton; Diaz de los Bernardos, Miriam; Urrutigoity, Martine; Claver, Carmen; Ruiz, Aurora; Godard, Cyril (2020). Efficient synthesis of chiral γ-aminobutyric esters: Via direct rhodium-catalysed enantioselective hydroaminomethylation of acrylates. Catalysis Science & Technology, 10(3), 630-634. DOI: 10.1039/c9cy01797f
    Paper original source: Catalysis Science & Technology. 10 (3): 630-634
    Article's DOI: 10.1039/c9cy01797f
    Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    Journal publication year: 2020
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2024-10-12
    URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / CUNILLERA MARTIN, ANTON / Godard, Cyril / Ruiz Manrique, Maria Aurora
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Acronym: ECO2VALCAT
    Publication Type: Journal Publications
    ISSN: 20444753
    Author, as appears in the article.: Cunillera, Anton; Diaz de los Bernardos, Miriam; Urrutigoity, Martine; Claver, Carmen; Ruiz, Aurora; Godard, Cyril
    Project code: CTQ2016-75016-R
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Materiais, Farmacia, Engenharias ii, Engenharias i, Ciências biológicas ii, Ciências biológicas i, Ciências agrárias i, Ciência de alimentos, Chemistry, physical, Catalysis, Biotecnología, Astronomia / física
    Author's mail: cyril.godard@urv.cat, mariaaurora.ruiz@urv.cat, carmen.claver@urv.cat

  • Keywords:

    Olefins
    Metal
    Ligands
    Hydroformylation
    Gaba(b) receptor
    Addiction
    Catalysis
    Chemistry
    Physical
    Química
    Materiais
    Farmacia
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Ciência de alimentos
    Biotecnología
    Astronomia / física

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