Author, as appears in the article.: Cunillera, Anton; Diaz de los Bernardos, Miriam; Urrutigoity, Martine; Claver, Carmen; Ruiz, Aurora; Godard, Cyril
Department: Química Física i Inorgànica
URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / CUNILLERA MARTIN, ANTON / Godard, Cyril / Ruiz Manrique, Maria Aurora
Project code: CTQ2016-75016-R
Keywords: Olefins Metal Ligands Hydroformylation Gaba(b) receptor Addiction
Abstract: This journal is © The Royal Society of Chemistry. The successful rhodium catalysed asymmetric intermolecular hydroaminomethylation (HAM) of alkenes using a single catalyst bearing the (R,R)-QuinoxP∗ ligand is reported. The HAM of α-alkyl acrylates is revealed to be an efficient tool for the regio- and enantioselective synthesis of γ-amino esters with ees up to 86%. HPNMR experiments provided insights into the reaction mechanism.
Thematic Areas: Química Materiais Farmacia Engenharias ii Engenharias i Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 20444753
Author's mail: cyril.godard@urv.cat mariaaurora.ruiz@urv.cat carmen.claver@urv.cat
Author identifier: 0000-0001-5762-4904 0000-0002-1563-292X 0000-0002-2518-7401
Record's date: 2024-10-12
Papper version: info:eu-repo/semantics/acceptedVersion
Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Catalysis Science & Technology. 10 (3): 630-634
APA: Cunillera, Anton; Diaz de los Bernardos, Miriam; Urrutigoity, Martine; Claver, Carmen; Ruiz, Aurora; Godard, Cyril (2020). Efficient synthesis of chiral γ-aminobutyric esters: Via direct rhodium-catalysed enantioselective hydroaminomethylation of acrylates. Catalysis Science & Technology, 10(3), 630-634. DOI: 10.1039/c9cy01797f
Acronym: ECO2VALCAT
Entity: Universitat Rovira i Virgili
Journal publication year: 2020
Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
Publication Type: Journal Publications
Repositori URV