Author, as appears in the article.: Salas, Daniela; Borrull, Francesc; Fontanals, Nuria; Maria Marce, Rosa
Department: Química Analítica i Química Orgànica
URV's Author/s: Borrull Ballarín, Francesc / Fontanals Torroja, Núria / Marcé Recasens, Rosa Maria / SALAS ACOSTA, DANIELA
Keywords: Waste-water Transformation products Stationary phases Solid-phase extraction Reversed-phase Methylamino-l-alanine Mass spectrometry Interaction lc Hydrophilic interaction liquid chromatography Hilic stationary phases Hilic mobile phases Fresh-water Environmental samples Emerging organic contaminants Contrast agents Artificial sweeteners
Abstract: © 2017 Elsevier B.V. Hydrophilic interaction liquid chromatography (HILIC) has gained widespread acceptance as an alternative to reversed-phase liquid chromatography (RPLC) for the retention and separation of polar compounds. Because a great number of emerging organic contaminants are polar, this represents progress in terms of solving most of the problems and limitations encountered in the conventional methods developed for their determination. In this review, recent HILIC applications developed in the environmental field are described, which are normally coupled with mass spectrometry, in order to reach the limits required to quantify contaminants present at trace levels and benefit from its capacity for confirmation. Special attention is paid to the stationary and mobile phases commonly used in terms of the advantages that they offer compared to reversed-phase columns and the high-water content mobile phases traditionally used in RPLC. The most important features related to the matrices and contaminants normally studied are also discussed, as well as the contribution of the HILIC mode towards reducing the matrix effect.
Thematic Areas: Spectroscopy Química Medicina ii Interdisciplinar Farmacia Environmental chemistry Engenharias iv Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, analytical Biotecnología Astronomia / física Analytical chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 01659936
Author's mail: nuria.fontanals@urv.cat nuria.fontanals@urv.cat rosamaria.marce@urv.cat francesc.borrull@urv.cat
Author identifier: 0000-0002-7534-1964 0000-0002-7534-1964 0000-0002-5667-2899 0000-0003-2718-9336
Record's date: 2024-10-12
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Trac-Trends In Analytical Chemistry. 94 141-149
APA: Salas, Daniela; Borrull, Francesc; Fontanals, Nuria; Maria Marce, Rosa (2017). Hydrophilic interaction liquid chromatography coupled to mass spectrometry-based detection to determine emerging organic contaminants in environmental samples. Trac-Trends In Analytical Chemistry, 94(), 141-149. DOI: 10.1016/j.trac.2017.07.017
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
Publication Type: Journal Publications
Repositori URV