Author, as appears in the article.: Salvado, Oriol; Fernandez, Elena;
Department: Química Física i Inorgànica
URV's Author/s: Fernández Gutiérrez, Maria Elena / Salvadó Ruiz, Oriol
Keywords: Stereoselective-synthesis Reagent Hydroboration Carbonyl-compounds
Abstract: We describe the preparation of densely functionalised 1,1-silylborylated trisubstituted alkenes, via a boron-Wittig reaction, between LiC(Bpin)(2)(SiMe3) and aliphatic or aromatic aldehydes. The condensation of diborylsilylmethide lithium salts with alpha,beta-unsaturated aldehydes provides a direct pathway to synthesize 1,1-silylborylated conjugated dienes and diynes.
Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: oriol.salvado@urv.cat oriol.salvado@urv.cat mariaelena.fernandez@urv.cat
Author identifier: 0000-0001-9025-1791
Record's date: 2024-07-27
Papper version: info:eu-repo/semantics/submittedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemical Communications. 57 (51): 6300-6303
APA: Salvado, Oriol; Fernandez, Elena; (2021). A modular olefination reaction between aldehydes and diborylsilylmethide lithium salts. Chemical Communications, 57(51), 6300-6303. DOI: 10.1039/d1cc01882e
Entity: Universitat Rovira i Virgili
Journal publication year: 2021
Publication Type: Journal Publications
Repositori URV