Author, as appears in the article.: Salvado, Oriol; Fernandez, Elena;

Department: Química Física i Inorgànica

URV's Author/s: Fernández Gutiérrez, Maria Elena

Keywords: Stereoselective-synthesis Reagent Hydroboration Carbonyl-compounds

Abstract: We describe the preparation of densely functionalised 1,1-silylborylated trisubstituted alkenes, via a boron-Wittig reaction, between LiC(Bpin)(2)(SiMe3) and aliphatic or aromatic aldehydes. The condensation of diborylsilylmethide lithium salts with alpha,beta-unsaturated aldehydes provides a direct pathway to synthesize 1,1-silylborylated conjugated dienes and diynes.

Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

Author's mail: mariaelena.fernandez@urv.cat

Author identifier: 0000-0001-9025-1791

Record's date: 2023-02-19

Papper version: info:eu-repo/semantics/submittedVersion

Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc01882e

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Chemical Communications. 57 (51): 6300-6303

APA: Salvado, Oriol; Fernandez, Elena; (2021). A modular olefination reaction between aldehydes and diborylsilylmethide lithium salts. Chemical Communications, 57(51), 6300-6303. DOI: 10.1039/d1cc01882e

Article's DOI: 10.1039/d1cc01882e

Entity: Universitat Rovira i Virgili

Journal publication year: 2021

Publication Type: Journal Publications