Articles producció científicaQuímica Física i Inorgànica

A modular olefination reaction between aldehydes and diborylsilylmethide lithium salts

  • Identification data

    Identifier:  imarina:9216862
    Handle: https://hdl.handle.net/20.500.11797/imarina9216862
    Authors:  Salvado, O; Fernández, E
    Abstract:
    We describe the preparation of densely functionalised 1,1-silylborylated trisubstituted alkenes, via a boron-Wittig reaction, between LiC(Bpin)(2)(SiMe3) and aliphatic or aromatic aldehydes. The condensation of diborylsilylmethide lithium salts with alpha,beta-unsaturated aldehydes provides a direct pathway to synthesize 1,1-silylborylated conjugated dienes and diynes.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc01882e
    APA: Salvado, O; Fernández, E (2021). A modular olefination reaction between aldehydes and diborylsilylmethide lithium salts. Chemical Communications, 57(51), 6300-6303. DOI: 10.1039/d1cc01882e
    Paper original source: Chemical Communications. 57 (51): 6300-6303
    Article's DOI: 10.1039/d1cc01882e
    Journal publication year: 2021-06-28
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/submittedVersion
    Record's date: 2026-05-09
    URV's Author/s: Fernández Gutiérrez, Maria Elena / Salvadó Ruiz, Oriol
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Salvado, O; Fernández, E
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Surfaces, coatings and films, Metals and alloys, Materials chemistry, General medicine, General chemistry, Electronic, optical and magnetic materials, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Ceramics and composites, Catalysis, Biotecnología, Astronomia / física
    Author's mail: oriol.salvado@alumni.urv.cat, mariaelena.fernandez@urv.cat, mariaelena.fernandez@urv.cat

  • Keywords:

    Stereoselective-synthesis
    Reagent
    Hydroboration
    Carbonyl-compounds
    Catalysis
    Ceramics and Composites
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Electronic
    Optical and Magnetic Materials
    Materials Chemistry
    Metals and Alloys
    Surfaces
    Coatings and Films
    General medicine
    General chemistry
    Chemistry (all)
    Biotecnología
    Astronomia / física

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