Author, as appears in the article.: Corro M; Salvado O; González S; Dominguez-Molano P; Fernández E
Department: Química Física i Inorgànica
URV's Author/s: Corro Morón, Macarena / Domínguez Molano, Paula / Fernández Gutiérrez, Maria Elena / González Morán, Sara / Salvadó Ruiz, Oriol
Keywords: Α-boryl carbanions Enantioselectivity Electrophilic trapping Diastereoselectivity Copper Alpha-boryl carbanions Allylic substitution olefination gem-diborylalkanes esters enantioselectivity enantioselective synthesis electrophilic trapping diborylmethane diastereoselectivity diastereo copper aldimines aldehydes 1,1-diborylalkanes
Abstract: The renaissance on the application of gem-diborylalkanes from 2010, has allowed the conquest of new synthetic application towards C−C and C−N bond formation. The activation of gem-diborylalkanes by Cu(I) catalysts, generates active borylalky copper(I) species that are able to trap several electrophilic reagents, in an efficient way. In addition, the modification of Cu(I) complexes with chiral ligands, induces asymmetric platforms towards the synthesis of enantioenriched organoboron compounds.
Thematic Areas: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: oriol.salvado@urv.cat paula.dominguez@urv.cat paula.dominguez@urv.cat sara.gonzalez@urv.cat oriol.salvado@urv.cat mariaelena.fernandez@urv.cat
Author identifier: 0000-0002-7309-8956 0000-0001-9025-1791
Record's date: 2024-07-27
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100296
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: European Journal Of Inorganic Chemistry. 2021 (28): 2802-2813
APA: Corro M; Salvado O; González S; Dominguez-Molano P; Fernández E (2021). Reactivity Trends with Borylalkyl Copper(I) Species. European Journal Of Inorganic Chemistry, 2021(28), 2802-2813. DOI: 10.1002/ejic.202100296
Article's DOI: 10.1002/ejic.202100296
Entity: Universitat Rovira i Virgili
Journal publication year: 2021
Publication Type: Journal Publications
Repositori URV