Author, as appears in the article.: Corro M; Salvado O; González S; Dominguez-Molano P; Fernández E

Department: Química Física i Inorgànica

URV's Author/s: Corro Morón, Macarena / Domínguez Molano, Paula / Fernández Gutiérrez, Maria Elena / González Morán, Sara / Salvadó Ruiz, Oriol

Keywords: Α-boryl carbanions Enantioselectivity Electrophilic trapping Diastereoselectivity Copper Alpha-boryl carbanions Allylic substitution olefination gem-diborylalkanes esters enantioselectivity enantioselective synthesis electrophilic trapping diborylmethane diastereoselectivity diastereo copper aldimines aldehydes 1,1-diborylalkanes

Abstract: The renaissance on the application of gem-diborylalkanes from 2010, has allowed the conquest of new synthetic application towards C−C and C−N bond formation. The activation of gem-diborylalkanes by Cu(I) catalysts, generates active borylalky copper(I) species that are able to trap several electrophilic reagents, in an efficient way. In addition, the modification of Cu(I) complexes with chiral ligands, induces asymmetric platforms towards the synthesis of enantioenriched organoboron compounds.

Thematic Areas: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

Author's mail: oriol.salvado@urv.cat sara.gonzalez@urv.cat paula.dominguez@urv.cat mariaelena.fernandez@urv.cat oriol.salvado@urv.cat sara.gonzalez@urv.cat paula.dominguez@urv.cat

Author identifier: 0000-0002-7309-8956 0000-0001-9025-1791 0000-0002-7309-8956

Record's date: 2023-04-22

Papper version: info:eu-repo/semantics/publishedVersion

Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100296

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: European Journal Of Inorganic Chemistry. 2021 (28): 2802-2813

APA: Corro M; Salvado O; González S; Dominguez-Molano P; Fernández E (2021). Reactivity Trends with Borylalkyl Copper(I) Species. European Journal Of Inorganic Chemistry, 2021(28), 2802-2813. DOI: 10.1002/ejic.202100296

Article's DOI: 10.1002/ejic.202100296

Entity: Universitat Rovira i Virgili

Journal publication year: 2021

Publication Type: Journal Publications