Articles producció científicaQuímica Física i Inorgànica

Reactivity Trends with Borylalkyl Copper(I) Species

  • Identification data

    Identifier:  imarina:9219136
    Handle: https://hdl.handle.net/20.500.11797/imarina9219136
    Authors:  Corro, M; Salvado, O; González, S; Dominguez-Molano, P; Fernández, E
    Abstract:
    The renaissance on the application of gem-diborylalkanes from 2010, has allowed the conquest of new synthetic application towards C−C and C−N bond formation. The activation of gem-diborylalkanes by Cu(I) catalysts, generates active borylalky copper(I) species that are able to trap several electrophilic reagents, in an efficient way. In addition, the modification of Cu(I) complexes with chiral ligands, induces asymmetric platforms towards the synthesis of enantioenriched organoboron compounds.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100296
    APA: Corro, M; Salvado, O; González, S; Dominguez-Molano, P; Fernández, E (2021). Reactivity Trends with Borylalkyl Copper(I) Species. European Journal Of Inorganic Chemistry, 2021(28), 2802-2813. DOI: 10.1002/ejic.202100296
    Paper original source: European Journal Of Inorganic Chemistry. 2021 (28): 2802-2813
    Article's DOI: 10.1002/ejic.202100296
    Journal publication year: 2021-07-26
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: Corro Morón, Macarena / Domínguez Molano, Paula / Fernández Gutiérrez, Maria Elena / González Morán, Sara / Salvadó Ruiz, Oriol
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Corro, M; Salvado, O; González, S; Dominguez-Molano, P; Fernández, E
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Inorganic chemistry, Engenharias iii, Engenharias ii, Chemistry, inorganic & nuclear, Astronomia / física
    Author's mail: paula.dominguez@estudiants.urv.cat, sara.gonzalez@urv.cat, oriol.salvado@alumni.urv.cat, mariaelena.fernandez@urv.cat, mariaelena.fernandez@urv.cat

  • Keywords:

    Α-boryl carbanions
    Enantioselectivity
    Electrophilic trapping
    Diastereoselectivity
    Copper
    Alpha-boryl carbanions
    Allylic substitution
    olefination
    gem-diborylalkanes
    esters
    enantioselective synthesis
    diborylmethane
    diastereo
    aldimines
    aldehydes
    1-diborylalkanes
    Chemistry
    Inorganic & Nuclear
    Inorganic Chemistry
    Engenharias iii
    Engenharias ii
    Astronomia / física

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