Articles producció científicaQuímica Analítica i Química Orgànica

Ligand-Controlled Regiodivergent Catalytic Amidation of Unactivated Secondary Alkyl Bromides

  • Identification data

    Identifier:  imarina:9226661
    Handle: https://hdl.handle.net/20.500.11797/imarina9226661
    Authors:  Tortajada, Andreu; Menezes Correia, Jose Tiago; Serrano, Eloisa; Monleon, Alicia; Tampieri, Alberto; Day, Craig S; Julia-Hernandez, Francisco; Martin, Ruben
    Abstract:
    A regiodivergent Ni-catalyzed amidation of unactivated secondary alkyl bromides is described. The site-selectivity of the amidation event is dictated by subtle differences on the ligand backbone, allowing introduction of the amide function at either the original sp(3) carbon-halide bond or at distal sp(3) C-H sites within an alkyl side-chain via chain-walking scenarios.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acscatal.1c02913?cookieSet=1
    APA: Tortajada, Andreu; Menezes Correia, Jose Tiago; Serrano, Eloisa; Monleon, Alicia; Tampieri, Alberto; Day, Craig S; Julia-Hernandez, Francisco; Martin, (2021). Ligand-Controlled Regiodivergent Catalytic Amidation of Unactivated Secondary Alkyl Bromides. Acs Catalysis, 11(16), 10223-10227. DOI: 10.1021/acscatal.1c02913
    Paper original source: Acs Catalysis. 11 (16): 10223-10227
    Article's DOI: 10.1021/acscatal.1c02913
    Journal publication year: 2021
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/submittedVersion
    Record's date: 2025-02-18
    URV's Author/s: Day, Craig / Monleón Getino, Antoni / Tampieri, Alberto / Tortajada Navarro, Andreu
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Tortajada, Andreu; Menezes Correia, Jose Tiago; Serrano, Eloisa; Monleon, Alicia; Tampieri, Alberto; Day, Craig S; Julia-Hernandez, Francisco; Martin, Ruben
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Materiais, Interdisciplinar, General chemistry, Engenharias ii, Ciências agrárias i, Chemistry, physical, Chemistry (miscellaneous), Chemistry (all), Catalysis, Astronomia / física
    Author's mail: antoni.monleon@urv.cat, craig.day@estudiants.urv.cat, alberto.tampieri@estudiants.urv.cat, alberto.tampieri@estudiants.urv.cat

  • Keywords:

    Remote
    Regiodivergent
    Reductive amidation
    Nickel
    Halides
    Functionalization
    Cross-coupling reactions
    Chemistry
    Chain walking
    Carboxylic-acids
    Carbonylation reactions
    Bonds
    Amides
    Amide bond
    Alkyl bromide
    Catalysis
    Chemistry (Miscellaneous)
    Physical
    Química
    Materiais
    Interdisciplinar
    General chemistry
    Engenharias ii
    Ciências agrárias i
    Chemistry (all)
    Astronomia / física

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