Author, as appears in the article.: Tortajada, Andreu; Menezes Correia, Jose Tiago; Serrano, Eloisa; Monleon, Alicia; Tampieri, Alberto; Day, Craig S.; Julia-Hernandez, Francisco; Martin, Ruben;
Department: Química Analítica i Química Orgànica
URV's Author/s: Day, Craig / Monleón Getino, Antoni / Tampieri, Alberto / Tortajada Navarro, Andreu
Keywords: Remote Regiodivergent Reductive amidation Nickel Halides Functionalization Cross-coupling reactions Chemistry Chain walking Carboxylic-acids Carbonylation reactions Bonds Amides Amide bond Alkyl bromide
Abstract: A regiodivergent Ni-catalyzed amidation of unactivated secondary alkyl bromides is described. The site-selectivity of the amidation event is dictated by subtle differences on the ligand backbone, allowing introduction of the amide function at either the original sp(3) carbon-halide bond or at distal sp(3) C-H sites within an alkyl side-chain via chain-walking scenarios.
Thematic Areas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: antoni.monleon@urv.cat craig.day@estudiants.urv.cat alberto.tampieri@estudiants.urv.cat alberto.tampieri@estudiants.urv.cat
Author identifier: 0000-0002-6931-0280
Record's date: 2024-07-27
Papper version: info:eu-repo/semantics/submittedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Acs Catalysis. 11 (16): 10223-10227
APA: Tortajada, Andreu; Menezes Correia, Jose Tiago; Serrano, Eloisa; Monleon, Alicia; Tampieri, Alberto; Day, Craig S.; Julia-Hernandez, Francisco; Martin (2021). Ligand-Controlled Regiodivergent Catalytic Amidation of Unactivated Secondary Alkyl Bromides. Acs Catalysis, 11(16), 10223-10227. DOI: 10.1021/acscatal.1c02913
Entity: Universitat Rovira i Virgili
Journal publication year: 2021
Publication Type: Journal Publications
Repositori URV