Unexpected Formation of Metallofulleroids from Multicomponent Reactions, with Crystallographic and Computational Studies of the Cluster Motion

Identifier:  imarina:9230630

Handle: https://hdl.handle.net/20.500.11797/imarina9230630

Authors:  Li, YB; Emge, TJ; Moreno-Vicente, A; Kopcha, WP; Sun, Y; Mansoor, IF; Lipke, MC; Hall, GS; Poblet, JM; Rodríguez-Fortea, A; Zhang, JY

Abstract:
New multicomponent reactions involving an isocyanide, terminal or internal alkynes, and endohedral metallofullerene (EMF) Lu3N@C80 yield metallofulleroids which are characterized by mass-spectrometry, HPLC, and multiple 1D and 2D NMR techniques. Single crystal studies revealed one ketenimine metallofulleroid has ordered Lu3N cluster which is unusual for EMF monoadducts. Computational analysis, based on crystallographic data, confirm that the endohedral cluster motion is controlled by the position of the exohedral organic appendants. Our findings provide a new functionalization reaction for EMFs, and a potential facile approach to freeze the endohedral cluster motion at relatively high temperatures.