Articles producció científica> Química Física i Inorgànica

Synthesis, spectroscopy, and efficient laser operation of "mixed" sesquioxide Tm:(Lu, Sc)(2)O-3 transparent ceramics

  • Identification data

    Identifier: imarina:9241991
    Authors:
    Jing, WeiLoiko, PavelSerres, Josep MariaWang, YichengVilejshikova, ElenaAguilo, MagdalenaDiaz, FrancescGriebner, UweHuang, HuiPetrov, ValentinMateos, Xavier
    Abstract:
    A novel transparent 4.76 at.% Tm:(Lu2/3Sc1/3)(2)O-3 "mixed" sequioxide ceramic is synthesized by hot isostatic pressing (HIP) at 1800 degrees C / 195 MPa in an Ar atmosphere. Its structure is studied by scanning electron microscopy, X-ray diffraction, and Raman spectroscopy. The spectroscopic properties of the Tm3+ ion are described within the Judd-Ofelt theory, which resulted in intensity parameters of Omega(2) = 2.429, Omega(4) = 1.078 and Omega(6) = 0.653 [10(-20) cm(2)]. For the F-3(4) -> H-3(6) transition, the maximum stimulated-emission cross-section sSE is 7.15 x 10(-21) cm(2) at 1951 nm. The radiative lifetime of the 3F4 state is 4.01 ms. Under diode-pumping at 802 nm, a microchip Tm:(Lu, Sc)O-2(3) ceramic laser generated similar to 1 W at 2100 nm with a slope efficiency of 24%. The spectroscopic and laser properties of the Tm:(Lu, Sc)O-2(3) ceramic are compared with those of a Tm: LuScO3 single crystal. The ceramic exhibits very broad and flat gain cross sections, which is promising for ultrashort pulse generation. (C) 2017 Optical Society of America under the terms of the OSA Open Access Publishing Agreement
  • Others:

    Author, as appears in the article.: Jing, Wei; Loiko, Pavel; Serres, Josep Maria; Wang, Yicheng; Vilejshikova, Elena; Aguilo, Magdalena; Diaz, Francesc; Griebner, Uwe; Huang, Hui; Petrov, Valentin; Mateos, Xavier
    Department: Química Física i Inorgànica
    URV's Author/s: Aguiló Díaz, Magdalena / Díaz González, Francisco Manuel / Mateos Ferré, Xavier / Serres Serres, Josep Maria
    Keywords: Yag Y2o3 Tm/lu2o3 Thin-disk laser Potassium Oscillation Luminescence Lu2o3 Light Intensities Cw Crystal-growth Absorption
    Abstract: A novel transparent 4.76 at.% Tm:(Lu2/3Sc1/3)(2)O-3 "mixed" sequioxide ceramic is synthesized by hot isostatic pressing (HIP) at 1800 degrees C / 195 MPa in an Ar atmosphere. Its structure is studied by scanning electron microscopy, X-ray diffraction, and Raman spectroscopy. The spectroscopic properties of the Tm3+ ion are described within the Judd-Ofelt theory, which resulted in intensity parameters of Omega(2) = 2.429, Omega(4) = 1.078 and Omega(6) = 0.653 [10(-20) cm(2)]. For the F-3(4) -> H-3(6) transition, the maximum stimulated-emission cross-section sSE is 7.15 x 10(-21) cm(2) at 1951 nm. The radiative lifetime of the 3F4 state is 4.01 ms. Under diode-pumping at 802 nm, a microchip Tm:(Lu, Sc)O-2(3) ceramic laser generated similar to 1 W at 2100 nm with a slope efficiency of 24%. The spectroscopic and laser properties of the Tm:(Lu, Sc)O-2(3) ceramic are compared with those of a Tm: LuScO3 single crystal. The ceramic exhibits very broad and flat gain cross sections, which is promising for ultrashort pulse generation. (C) 2017 Optical Society of America under the terms of the OSA Open Access Publishing Agreement
    Thematic Areas: Química Optics Materials science, multidisciplinary Materiais Interdisciplinar Engenharias iv Engenharias iii Engenharias ii Electronic, optical and magnetic materials Biotecnología Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: josepmaria.serres@urv.cat magdalena.aguilo@urv.cat xavier.mateos@urv.cat f.diaz@urv.cat
    Author identifier: 0000-0002-4299-538X 0000-0001-6130-9579 0000-0003-1940-1990 0000-0003-4581-4967
    Record's date: 2024-10-19
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://opg.optica.org/ome/fulltext.cfm?uri=ome-7-11-4192&id=376519
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Optical Materials Express. 7 (11): 4192-4202
    APA: Jing, Wei; Loiko, Pavel; Serres, Josep Maria; Wang, Yicheng; Vilejshikova, Elena; Aguilo, Magdalena; Diaz, Francesc; Griebner, Uwe; Huang, Hui; Petrov (2017). Synthesis, spectroscopy, and efficient laser operation of "mixed" sesquioxide Tm:(Lu, Sc)(2)O-3 transparent ceramics. Optical Materials Express, 7(11), 4192-4202. DOI: 10.1364/OME.7.004192
    Article's DOI: 10.1364/OME.7.004192
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    Publication Type: Journal Publications
  • Keywords:

    Electronic, Optical and Magnetic Materials,Materials Science, Multidisciplinary,Optics
    Yag
    Y2o3
    Tm/lu2o3
    Thin-disk laser
    Potassium
    Oscillation
    Luminescence
    Lu2o3
    Light
    Intensities
    Cw
    Crystal-growth
    Absorption
    Química
    Optics
    Materials science, multidisciplinary
    Materiais
    Interdisciplinar
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Electronic, optical and magnetic materials
    Biotecnología
    Astronomia / física
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