Articles producció científica> Química Física i Inorgànica

Multicomponent Reactions among Alkyl Isocyanides, sp Reactants, and sp 2Carbon Cages

  • Identification data

    Identifier: imarina:9245953
    Handle: https://hdl.handle.net/20.500.11797/imarina9245953
    Authors:
    Li, YanbangKopcha, William PRodriguez-Fortea, AntonioZhang, Jianyuan
    Abstract:
    We explored the reactivity and substrate scope of the reactions among an alkyl isocyanide, an sp-hybridized reactant (i.e. alkyne or allene), and a carbon cage, as a new approach to functionalize fullerenes and metallofullerenes. This account summarizes the key findings in our recent published work, and some original data for the reaction involving an isocyanide, allenes, and metallofullerene Lu3N@C80. 1 Introduction 2 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Alkynes 3 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Allenes 4 Conclusion.

  • Others:

    Author, as appears in the article.: Li, Yanbang; Kopcha, William P; Rodriguez-Fortea, Antonio; Zhang, Jianyuan
    Department: Química Física i Inorgànica
    URV's Author/s: Alkhoury, Nadine / Rodríguez Fortea, Antonio / Zhang, Jiayu
    Keywords: Multicomponent reaction Isocyanide Fullerenes Endohedral metallofullerenes Endohedral Cluster motion sc3n-at-c-80 regioselective synthesis reactivity multi-component reaction m3n-at-i-h-c-80 m functionalization fullerenes fullerene endohedral derivatives crystallographic characterization cluster motion 1,3-dipolar cycloaddition
    Abstract: We explored the reactivity and substrate scope of the reactions among an alkyl isocyanide, an sp-hybridized reactant (i.e. alkyne or allene), and a carbon cage, as a new approach to functionalize fullerenes and metallofullerenes. This account summarizes the key findings in our recent published work, and some original data for the reaction involving an isocyanide, allenes, and metallofullerene Lu3N@C80. 1 Introduction 2 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Alkynes 3 Isocyanide-Induced Fullerene/EMF Reactions with Substituted Allenes 4 Conclusion.
    Thematic Areas: Química Organic chemistry Medicina ii Medicina i Materiais Interdisciplinar Farmacia Engenharias ii Ciências biológicas ii Ciências biológicas i Ciência de alimentos Chemistry, organic Biotecnología
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: nadine.alkhoury@estudiants.urv.cat nadine.alkhoury@estudiants.urv.cat nadine.alkhoury@estudiants.urv.cat nadine.alkhoury@estudiants.urv.cat jiayu.zhang@estudiants.urv.cat antonio.rodriguezf@urv.cat
    Author identifier: 0000-0001-5884-5629
    Record's date: 2024-10-12
    Papper version: info:eu-repo/semantics/acceptedVersion
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Synlett. 33 (10): 907-912
    APA: Li, Yanbang; Kopcha, William P; Rodriguez-Fortea, Antonio; Zhang, Jianyuan (2022). Multicomponent Reactions among Alkyl Isocyanides, sp Reactants, and sp 2Carbon Cages. Synlett, 33(10), 907-912. DOI: 10.1055/a-1741-9000
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2022
    Publication Type: Journal Publications

  • Keywords:

    Chemistry, Organic,Organic Chemistry
    Multicomponent reaction
    Isocyanide
    Fullerenes
    Endohedral metallofullerenes
    Endohedral
    Cluster motion
    sc3n-at-c-80
    regioselective synthesis
    reactivity
    multi-component reaction
    m3n-at-i-h-c-80 m
    functionalization
    fullerenes
    fullerene
    endohedral
    derivatives
    crystallographic characterization
    cluster motion
    1,3-dipolar cycloaddition
    Química
    Organic chemistry
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Ciência de alimentos
    Chemistry, organic
    Biotecnología

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