Articles producció científica> Química Analítica i Química Orgànica

Higher Acenes by On-Surface Dehydrogenation: From Heptacene to Undecacene

  • Identification data

    Identifier: imarina:9280618
    Authors:
    Zuzak RDorel RKolmer MSzymonski MGodlewski SEchavarren AM
    Abstract:
    A unified approach to the synthesis of the series of higher acenes up to previously unreported undecacene has been developed through the on-surface dehydrogenation of partially saturated precursors. These molecules could be converted into the parent acenes by both atomic manipulation with the tip of a scanning tunneling and atomic force micro-scope (STM/AFM) as well as by on-surface annealing. The structure of the generated acenes has been visualized by high-resolution non-contact AFM imaging and the evolution of the transport gap with the increase of the number of fused benzene rings has been determined on the basis of scanning tunneling spectroscopy (STS) measurements. A.
  • Others:

    Author, as appears in the article.: Zuzak R; Dorel R; Kolmer M; Szymonski M; Godlewski S; Echavarren AM
    Department: Química Analítica i Química Orgànica
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Keywords: Undecacene Surface chemistry Dehydrogenation Atomic force microscopy Acenes
    Abstract: A unified approach to the synthesis of the series of higher acenes up to previously unreported undecacene has been developed through the on-surface dehydrogenation of partially saturated precursors. These molecules could be converted into the parent acenes by both atomic manipulation with the tip of a scanning tunneling and atomic force micro-scope (STM/AFM) as well as by on-surface annealing. The structure of the generated acenes has been visualized by high-resolution non-contact AFM imaging and the evolution of the transport gap with the increase of the number of fused benzene rings has been determined on the basis of scanning tunneling spectroscopy (STS) measurements. A.
    Thematic Areas: Química Physics, condensed matter Physics, applied Nanoscience and nanotechnology Nanoscience & nanotechnology Medicina ii Mechanics of materials Mechanical engineering Materials science, multidisciplinary Materials science (miscellaneous) Materials science (all) Materials science Materiais Interdisciplinar General materials science Engenharias iv Engenharias iii Engenharias ii Chemistry, physical Chemistry, multidisciplinary Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: antoniomaria.echavarren@urv.cat
    Author identifier: 0000-0002-6418-7930
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201802040
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Advanced Materials. 57 (33): 10660-10665
    APA: Zuzak R; Dorel R; Kolmer M; Szymonski M; Godlewski S; Echavarren AM (2018). Higher Acenes by On-Surface Dehydrogenation: From Heptacene to Undecacene. Advanced Materials, 57(33), 10660-10665. DOI: 10.1002/ANGE.201802040
    Article's DOI: 10.1002/ANGE.201802040
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2018
    Publication Type: Journal Publications
  • Keywords:

    Chemistry, Multidisciplinary,Chemistry, Physical,Materials Science,Materials Science (Miscellaneous),Materials Science, Multidisciplinary,Mechanical Engineering,Mechanics of Materials,Nanoscience & Nanotechnology,Nanoscience and Nanotechnology,Physics, Applied,Physics, Condensed Matter
    Undecacene
    Surface chemistry
    Dehydrogenation
    Atomic force microscopy
    Acenes
    Química
    Physics, condensed matter
    Physics, applied
    Nanoscience and nanotechnology
    Nanoscience & nanotechnology
    Medicina ii
    Mechanics of materials
    Mechanical engineering
    Materials science, multidisciplinary
    Materials science (miscellaneous)
    Materials science (all)
    Materials science
    Materiais
    Interdisciplinar
    General materials science
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Chemistry, physical
    Chemistry, multidisciplinary
    Astronomia / física
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