Author, as appears in the article.: Salto, Joan; Biosca, Maria; Pamies, Oscar; Dieguez, Montserrat;
Department: Química Física i Inorgànica
URV's Author/s: Biosca Brull, Maria / Diéguez Fernández, Montserrat / Pamies Ollé, Oscar / Saltó De La Torre, Joan
Keywords: Tricarbocycles Sesquiterpene Pauson-khand reactions Pauson-khand Metal-catalysis Ligands Design Cyclizations Cobalt Asymmetric-synthesis Allylic substitution
Abstract: A set of complex tricyclic compounds containing several functional groups and multiple stereogenic centers has been prepared in only two steps with excellent diastereo- and enantioselectivities. The synthesis takes advantage of the highly versatile and enantioselective Pd-catalyzed allylic substitution of simple cyclic allylic acetates or carbonates to form chiral 1,6-, 1,7- and 1,8-enynes, which are then diastereoselectively transformed to the corresponding cyclopentenone- and cyclobutene-based tricyclic compounds.
Thematic Areas: Química Organic chemistry Materiais Engenharias iv Engenharias ii Ciências biológicas ii Ciência de alimentos Chemistry, organic Chemistry, applied Catalysis Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: maria.biosca@urv.cat joan.salto@estudiants.urv.cat joan.salto@estudiants.urv.cat oscar.pamies@urv.cat montserrat.dieguez@urv.cat
Author identifier: 0000-0002-9116-6318 0000-0003-4846-8473 0000-0003-4846-8473 0000-0002-2352-8508 0000-0002-8450-0656
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.202200685
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Advanced Synthesis & Catalysis. 364 (21): 3682-3689
APA: Salto, Joan; Biosca, Maria; Pamies, Oscar; Dieguez, Montserrat; (2022). Synthesis of Chiral, Fused Tricyclic Molecules by Sequential Metal-Catalyzed Reactions of Simple Substrates. Advanced Synthesis & Catalysis, 364(21), 3682-3689. DOI: 10.1002/adsc.202200685
Article's DOI: 10.1002/adsc.202200685
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV